Efficient Synthesis of Optically Pure Mono- and Binuclear Macrocyclic Polylactones from Castor Oil and Sebacic Acid

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Doklady Chemistry Pub Date : 2024-01-31 DOI:10.1134/S0012500823601031

G. Yu. Ishmuratov, N. I. Medvedeva, K. M. Saitov, M. P. Yakovleva, I. S. Nazarov, A. G. Tolstikov

引用次数: 0

Abstract

An efficient synthesis of optically pure macrocyclic mono- and binuclear polylactones has been proposed. The synthesis is based on the condensation of natural triol, castor oil, with sebacoyl dichloride in 1 : 1 or 1 : 2 ratios in boiling carbon tetrachloride in the presence of triethylamine and N,N-dimethylaminopyridine as a catalyst.

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利用蓖麻油和癸二酸高效合成光学纯度较高的单核和双核大环多内酯

摘要提出了一种高效合成光学纯大环单核和双核多内酯的方法。该合成方法是在三乙胺和 N,N-二甲氨基吡啶作为催化剂的存在下，在沸腾的四氯化碳中以 1 : 1 或 1 : 2 的比例缩合天然三醇--蓖麻油和癸二酸二氯酯。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Doklady Chemistry 化学-化学综合

CiteScore

1.20

自引率

12.50%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.