Magnetic Interparticle Interactions and Superparamagnetic Blocking of Powder Systems of Biogenic Ferrihydrite Nanoparticles

IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY
A. A. Krasikov, Yu. V. Knyazev, D. A. Balaev, S. V. Stolyar, V. P. Ladygina, A. D. Balaev, R. S. Iskhakov
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Abstract

The magnetic-field dependence of the superparamagnetic-blocking temperature TB of systems of antiferromagnetically ordered ferrihydrite nanoparticles has been investigated and analyzed. We studied two powder systems of nanoparticles: particles of “biogenic” ferrihydrite (with an average size of 2.7 nm), released as a result of vital functions of bacteria and coated with a thin organic shell, and particles of biogenic ferrihydrite subjected to low-temperature annealing, which cause an increase in the average particle size (to 3.8 nm) and burning out of the organic shell. The character of the temperature dependences of magnetization, measured after cooling in a weak field, as well as the shape of the obtained dependences TB(H), demonstrate peculiar features, indicating the influence of magnetic interparticle interactions. A detailed analysis of the dependences TB(H) within the random magnetic anisotropy model made it possible to estimate quantitatively the intensity of magnetic particle–particle interactions and determine the magnetic anisotropy constants of individual ferrihydrite particles.

Abstract Image

生物铁氧体纳米粒子粉末系统的磁性粒子间相互作用和超顺磁性阻塞
摘要 研究和分析了反铁磁有序纳米铁酸盐体系的超顺磁性阻滞温度 TB 的磁场依赖性。我们研究了两种纳米颗粒粉末体系:一种是 "生物 "铁氧体颗粒(平均粒径为 2.7 nm),这种颗粒是由于细菌的生命机能而释放出来的,表面包裹着一层薄薄的有机外壳;另一种是生物铁氧体颗粒,这种颗粒经过低温退火处理后,平均粒径增大(达到 3.8 nm),有机外壳烧毁。在弱磁场中冷却后测量的磁化率随温度变化的特征,以及所获得的随温度变化的 TB(H) 的形状,都显示出特殊的特征,表明磁性粒子间相互作用的影响。通过详细分析随机磁各向异性模型中的 TB(H) 相关性,可以定量估算磁性粒子间相互作用的强度,并确定单个无水铁氧体粒子的磁各向异性常数。
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来源期刊
CiteScore
1.90
自引率
9.10%
发文量
130
审稿时长
3-6 weeks
期刊介绍: Journal of Experimental and Theoretical Physics is one of the most influential physics research journals. Originally based on Russia, this international journal now welcomes manuscripts from all countries in the English or Russian language. It publishes original papers on fundamental theoretical and experimental research in all fields of physics: from solids and liquids to elementary particles and astrophysics.
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