Calculation of Thermochemical and Detonation Parameters of Azido-Acetylenic Derivatives of s-Triazine

IF 0.9 4区工程技术 Q4 ENERGY & FUELS

Combustion, Explosion, and Shock Waves Pub Date : 2023-12-01 DOI:10.1134/s0010508223060060

引用次数: 0

Abstract

The properties of azido-acetylenic derivatives of s-triazine containing various combinations of propynyloxy, propynylamino, N-methyl-propynylamino, and azido groups have been studied, and their enthalpy of formation in the condensed phase, density, and impact and friction sensitivities have been determined. Based on these data, the energy parameters of detonation, combustion, and adiabatic transformation for individual compounds and their compositions with the binder SKI-3 isoprene rubber have been calculated. The results of the integrated experimental and theoretical studies suggest a high heat of combustion of the investigated individual compounds and compositions based on them.

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s-Triazine 的叠氮乙酰基衍生物的热化学和引爆参数计算

摘要研究了含有不同丙炔氧基、丙炔氨基、N-甲基丙炔氨基和叠氮基团组合的 s-三嗪叠氮乙炔衍生物的特性，并确定了它们在凝聚相中的形成焓、密度以及冲击和摩擦敏感性。根据这些数据，计算了单个化合物及其与粘合剂 SKI-3 异戊二烯橡胶组成的起爆、燃烧和绝热转化的能量参数。综合实验和理论研究的结果表明，所研究的单个化合物和以它们为基础的混合物具有很高的燃烧热。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Combustion, Explosion, and Shock Waves 工程技术-材料科学：综合

CiteScore

1.60

自引率

16.70%

发文量

审稿时长

5.7 months

期刊介绍： Combustion, Explosion, and Shock Waves a peer reviewed journal published in collaboration with the Siberian Branch of the Russian Academy of Sciences. The journal presents top-level studies in the physics and chemistry of combustion and detonation processes, structural and chemical transformation of matter in shock and detonation waves, and related phenomena. Each issue contains valuable information on initiation of detonation in condensed and gaseous phases, environmental consequences of combustion and explosion, engine and power unit combustion, production of new materials by shock and detonation waves, explosion welding, explosive compaction of powders, dynamic responses of materials and constructions, and hypervelocity impact.