Use of near-infrared spectroscopy for the online monitoring of natural gas composition (hydrocarbons, water and CO2 content) at high pressure

Abstract

The natural gas production from Brazilian pre-salt fields imposed new challenges for petrochemical industry. Actual treatment facilities are not adequate for this new scenario and studies have been conducted to apply new adsorbents materials and membranes for water and CO₂ removal from natural gas at high pressures. To better develop such investigations, sensors for on-line monitoring of natural gas properties like CO₂ and water content are important, since their presence affects the quality of the final product. Near infrared (NIR) spectroscopy associated to chemometric models (partial least squares) were employed for on-line monitoring of representative natural gas systems (methane/CO₂, methane/water and methane/CO₂/water) and a real natural gas at temperature and pressure ranges from 20 to 60 °C and 10 to 200 bar, respectively, water content up to gas saturation and CO₂ content up to 50 wt%. Water solubility values used as reference for NIR Spectrometer calibration in model systems were taken from the literature and for real natural gas calculated with Cubic Plus Association (CPA) Equation of State (EoS), while CO₂ content was experimentally controlled aiming to calibrate the chemometric models in the full range of pressure and temperature. Several strategies were adopted for the chemometric model’s development to obtain the best correlation between NIR spectra and experimental data. Results indicate good correlation in both calibration and validation steps attaining linear correlation coefficients (R²) higher than 0.96 for all systems investigated. The proposed methodology is a potential tool for on-line monitoring of natural gas composition, including CO₂ and water content, at high-pressures and can be applied at petrochemical industries or in laboratories, dispensing sampling or any sample preparation.