Machining of TiAl6V4 Using Lubricants Containing Renewable Microalgae-Born Performance Additives

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Thomas Koch, Dominik Wenzel, Ralf Gläbe
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Abstract

Abstract Titanium and its alloys represent a special class of materials. A density of 4.81 g/cm3, a tensile strength of over 1,200 MPa, a fatigue strength greater than that of steel, a low modulus of elasticity and its self-passivating, inert surface make titanium an ideal material for lightweight structures in aerospace, marine applications, the chemical industry and medical implants. Although titanium is inert in its oxidised state, its nascent surface created in machining reacts with almost everything in its environment, including the tool. Moreover, its poor thermal conductivity results in high thermal stress on the tools. Overall, these properties lead to high wear rates and result in the requirement for finding a particularised solution for processes such as milling that involve the need to overcome such challenges. Such processes therefore require lubricants with well-selected performance additives. However, most of these performance additives are based on mineral oil and thus come from a non-renewable resource. In the presented work, environmental-friendly alternatives to conventional mineral oil-based performance additives were investigated. Due to the working mechanisms of performance additives in machining, this work focusses on sulphur- and phosphorus-containing polysaccharides and proteins from microalgae. It has been successfully shown that lubricants using extracts from microalgae as performance additives can be used for high-speed milling (HSC) of TiAl6V4. The investigated extracts were able to reach the performance level of conventional additives in terms of tool lifetime and wear. The results obtained show that appropriate alternatives to mineral oil-based additives exist from renewable raw-material sources.
使用含可再生微藻高性能添加剂的润滑油加工 TiAl6V4
摘要 钛及其合金是一类特殊的材料。钛的密度为 4.81 克/立方厘米,抗拉强度超过 1,200 兆帕,疲劳强度超过钢,弹性模量低,表面具有自钝化和惰性,因此是航空航天、海洋应用、化学工业和医疗植入物领域轻质结构的理想材料。虽然钛在氧化状态下是惰性的,但其在加工过程中形成的新生表面几乎会与周围环境中的一切物质(包括工具)发生反应。此外,钛的导热性较差,会对工具产生较高的热应力。总之,这些特性会导致高磨损率,因此需要为需要克服这些挑战的铣削等工艺找到专门的解决方案。因此,此类工艺需要使用经过精心挑选的高性能添加剂的润滑油。然而,这些高性能添加剂大多以矿物油为基础,因此来自不可再生资源。本文研究了传统矿物油基高性能添加剂的环保型替代品。鉴于高性能添加剂在机械加工中的工作机制,这项工作的重点是微藻中含硫和磷的多糖和蛋白质。研究成功表明,使用微藻提取物作为高性能添加剂的润滑剂可用于 TiAl6V4 的高速铣削 (HSC)。在工具寿命和磨损方面,所研究的提取物能够达到传统添加剂的性能水平。研究结果表明,可再生原料来源是矿物油基添加剂的适当替代品。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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