Efficiency of Food Waste Activated Carbon in Treating Biodiesel Plant Effluent: Impact on Process Conditions and NaOH Recovery

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Abstract

In work illustrated, the mixed food reject was carbonized and further activated with zinc chloride for biodiesel washwater treatment experiments. Biodiesel washwater is one of the significant side streams generated during biodiesel production from waste cooking oil. The food waste activated carbon (FWAC) and commercial activated carbon (CAC) were analyzed for structural and surface morphology using X-ray diffraction (XRD), Filed emission scanning microscopy (FE-SEM) and IR-Raman spectroscopy. The adsorption experiments were performed at 10 to 50 minutes with an adsorbent dosage of 0.1 to 0.5 in 100 mL of biodiesel wash water. pH, Turbidity and Total dissolved solid of biodiesel plant effluent before and after adsorption experiments were determined. Food waste-activated carbon used for the study reduced the effluent pH from 11.5 to 7, Turbidity from 435 NTU to 1 NTU and TDS from 1140 mg/L to 145 mg/L. The feasibility of NaOH recovery from biodiesel wash water was also studied.
厨余活性炭处理生物柴油厂废水的效率:对工艺条件和 NaOH 回收的影响
在图示的工作中,混合食物垃圾被碳化,并用氯化锌进一步活化,用于生物柴油洗涤水处理实验。生物柴油洗涤水是利用废弃食用油生产生物柴油过程中产生的重要副流之一。利用 X 射线衍射 (XRD)、栅极发射扫描显微镜 (FE-SEM) 和红外-拉曼光谱分析了厨余活性炭 (FWAC) 和商用活性炭 (CAC) 的结构和表面形态。吸附实验在 100 毫升生物柴油洗涤水中进行,吸附剂用量为 0.1 至 0.5,吸附时间为 10 至 50 分钟,并测定了吸附实验前后生物柴油厂污水的 pH 值、浊度和总溶解固体。研究中使用的厨余活性炭将污水的 pH 值从 11.5 降至 7,浊度从 435 NTU 降至 1 NTU,TDS 从 1140 mg/L 降至 145 mg/L。此外,还研究了从生物柴油洗涤水中回收 NaOH 的可行性。
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