Nano Metal Oxide Frameworks (NOF): Development of New Heterogeneous Catalyst for the Synthesis of Furan Derivatives from Glucose

R. Jaiswal, Melad Shaikh, Kalluri V.S. Ranganath
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Abstract

A surface modification approach has prepared a nanostructured organic framework connecting two metal oxide NPs. The surface modifier attached two metal oxide NPs via molecular interaction to generate modular structures of fiber, rod, or sponge materials. Thus, obtained hybrid systems have been confirmed through FT-IR, TGA, PXRD, and SEM. Metal oxides such as Fe3O4 and MgO generated mixed materials via the surface modification approach. Thus, obtained materials have been successfully used to dehydrate biomass-derived glucose. The products HMF and subsequently partially oxidized product DFF are considered to be valuable compounds not only in fuel technology but also in the pharmaceutical industry.
纳米金属氧化物框架(NOF):开发从葡萄糖合成呋喃衍生物的新型异相催化剂
一种表面改性方法制备出了连接两个金属氧化物 NP 的纳米结构有机框架。表面改性剂通过分子相互作用将两个金属氧化物 NPs 连接起来,从而生成纤维、棒状或海绵状的模块化结构材料。因此,所获得的混合系统已通过 FT-IR、TGA、PXRD 和 SEM 得到证实。Fe3O4 和 MgO 等金属氧化物通过表面改性方法生成了混合材料。因此,所获得的材料已成功用于生物质葡萄糖的脱水。产品 HMF 和随后的部分氧化产品 DFF 被认为是有价值的化合物,不仅应用于燃料技术,还应用于制药业。
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