Anti-deformation performance of asphalt modified by carbon black extracted from waste cooking oil pyrolysis waste tires rubber

Yiling Li, Yankai Qin
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Abstract

As a promising renewable resource, waste tire rubber powder has been utilized to enhance asphalt performance but it has compatibility concerns with matrix asphalt. To solve the phase separation between crumb tire rubber (CTR) and asphalt, waste cooking oil (WCO) has been successfully employed as the solvent to desulfurize crumb rubber. However, about 30 % of carbon black is wrapped in crumb rubber, which has a high recycling value. The cross-linking network structure of the crumb rubber can be loosened by waste cooking oil, and the carbon black will gradually peel off. This study desulfurizes crumb rubber with waste cooking oil at 180 ℃, and the carbon black produced by the evolution of rubber structure was separated by Soxhlet extraction. The rubber-cracked carbon black (RCCB) and the industrial carbon black N330 were added to asphalt, and the impact of the two different carbon black on the anti-deformation of asphalt was analyzed by dynamic shear rheometer (DSR). The results indicated that at the same dosage of 5 %, the carbon black separated from rubber will weaken the deformation resistance of asphalt at high temperatures, rather than improving it like N330 produced in the industry.
从废食用油热解废轮胎橡胶中提取的炭黑改性沥青的抗变形性能
作为一种前景广阔的可再生资源,废轮胎橡胶粉已被用于提高沥青的性能,但它与基质沥青之间存在相容性问题。为解决轮胎橡胶(CTR)与沥青之间的相分离问题,已成功采用废食用油(WCO)作为溶剂对轮胎橡胶进行脱硫处理。然而,约 30% 的炭黑被包裹在具有较高回收价值的轮胎橡胶中。废食用油会使橡胶屑的交联网络结构松散,炭黑会逐渐脱落。本研究用废食用油在 180 ℃ 下对橡胶屑进行脱硫,并通过索氏提取法分离橡胶结构演变产生的炭黑。将橡胶裂解炭黑(RCCB)和工业炭黑 N330 加入沥青中,用动态剪切流变仪(DSR)分析了两种不同炭黑对沥青抗变形的影响。结果表明,在相同用量(5%)的情况下,从橡胶中分离出来的炭黑会削弱沥青在高温下的抗变形能力,而不是像工业生产的 N330 那样改善沥青的抗变形能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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