Reduction of hydrogen absorption into materials of membrane electrode assemblies in hydrogen generators

M. Lebedeva, A. Ragutkin, I. M. Sidorov, N. A. Yashtulov
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Abstract

Objectives. To investigate the possibility of preventing hydrogen absorption into the functional structural materials of hydrogen-generating membrane electrode assemblies based on porous nickel, carbon black, and reduced graphene oxide with platinum–nickel and palladium–nickel nanoparticles.Methods. The hydrogen absorption into materials of membrane electrode assemblies of alkaline electrolyzers was evaluated using an electrolyzer with variable temperature, reagent feed rate, and gas content.Results. The study established the need to use reduced graphene oxide, in order to reduce hydrogen absorption and degradation of hydrogen-generating membrane electrode assemblies.Conclusions. The service life test results and performance of the designed variants of prototypes of membrane electrode assemblies with nanostructured electrodes based on reduced graphene oxide, preventing hydrogen absorption into functional materials and their degradation, demonstrated the creation of hydrogen generators with high energy efficiency shows potential.
减少氢气发生器中膜电极组件材料对氢气的吸收
研究目的研究防止氢气吸收到基于多孔镍、炭黑和具有铂镍和钯镍纳米颗粒的还原氧化石墨烯的制氢膜电极组件的功能结构材料中的可能性。使用温度、试剂进料速度和气体含量可变的电解槽,对碱性电解槽膜电极组件材料的氢气吸收情况进行了评估。研究确定了使用还原氧化石墨烯的必要性,以减少氢气吸收和制氢膜电极组件的降解。基于还原氧化石墨烯的纳米结构电极原型设计变体的使用寿命测试结果和性能,可防止功能材料吸氢和降解,这表明具有高能效的氢气发生器的制造是有潜力的。
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