{"title":"Mathematical modeling and evaluation of permeation and membrane separation performance for Fischer–Tropsch products in a hydrophilic membrane reactor","authors":"Dounia Alihellal, Sabrina Hadjam, Lemnouer Chibane","doi":"10.1515/cppm-2023-0016","DOIUrl":null,"url":null,"abstract":"Abstract A mathematical model was constructed to estimate the performance of an MFI-membrane reactor used for Fischer–Tropsch synthesis to produce a mixture of liquid hydrocarbons. In order to accurately evaluate the reactor’s performance a parametric study was performed. Under certain operational conditions, such as the total initial pressure in the reaction zone (1–4 MPa) and the hydrogen/carbon monoxide ratio (H2/CO: 1 to 2) on the performance of the studied reactor. The selectivity (productivity) of the hydrocarbon products (S i ), the quantity of hydrocarbons permiated (θ i ) and the separation factors of each space (α i ) were predicted. With increasing pressure, it is observed that θ CO and θ H 2 ${\\theta }_{{H}_{2}}$ are decreasing from 0.62 to 0.45 and from 0.55 to 0.49 respectively. However, as the H2/CO ratio rises, this measurement shows a slight increase. Aside from, the separation factors of the majority of the current species are unaffected by the H2/CO ratio increasing, while the separation factors of carbon monoxide and hydrogen are increasing. Similarly the selectivity of water, methane, carbon dioxide and ethane increases with increasing H2/CO ratio. Based on these findings it is revealed that the membrane can enable permeability for all species present in the products mixture with varying separation factors, and that the ability to separate species other than water from the reaction side is essentially non-existent.","PeriodicalId":9935,"journal":{"name":"Chemical Product and Process Modeling","volume":"30 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Product and Process Modeling","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/cppm-2023-0016","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract A mathematical model was constructed to estimate the performance of an MFI-membrane reactor used for Fischer–Tropsch synthesis to produce a mixture of liquid hydrocarbons. In order to accurately evaluate the reactor’s performance a parametric study was performed. Under certain operational conditions, such as the total initial pressure in the reaction zone (1–4 MPa) and the hydrogen/carbon monoxide ratio (H2/CO: 1 to 2) on the performance of the studied reactor. The selectivity (productivity) of the hydrocarbon products (S i ), the quantity of hydrocarbons permiated (θ i ) and the separation factors of each space (α i ) were predicted. With increasing pressure, it is observed that θ CO and θ H 2 ${\theta }_{{H}_{2}}$ are decreasing from 0.62 to 0.45 and from 0.55 to 0.49 respectively. However, as the H2/CO ratio rises, this measurement shows a slight increase. Aside from, the separation factors of the majority of the current species are unaffected by the H2/CO ratio increasing, while the separation factors of carbon monoxide and hydrogen are increasing. Similarly the selectivity of water, methane, carbon dioxide and ethane increases with increasing H2/CO ratio. Based on these findings it is revealed that the membrane can enable permeability for all species present in the products mixture with varying separation factors, and that the ability to separate species other than water from the reaction side is essentially non-existent.
期刊介绍:
Chemical Product and Process Modeling (CPPM) is a quarterly journal that publishes theoretical and applied research on product and process design modeling, simulation and optimization. Thanks to its international editorial board, the journal assembles the best papers from around the world on to cover the gap between product and process. The journal brings together chemical and process engineering researchers, practitioners, and software developers in a new forum for the international modeling and simulation community. Topics: equation oriented and modular simulation optimization technology for process and materials design, new modeling techniques shortcut modeling and design approaches performance of commercial and in-house simulation and optimization tools challenges faced in industrial product and process simulation and optimization computational fluid dynamics environmental process, food and pharmaceutical modeling topics drawn from the substantial areas of overlap between modeling and mathematics applied to chemical products and processes.