An Experimental Method to Evaluate the Contribution of Wood Substrate and Coating Film to the Light Induced Colour Changes of Wood Surfaces

Jr. Torcătoru, M.C. Timar
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Abstract

The paper presents an original laboratory method developed to determine and compare the light-induced colour changes of uncoated and coated wood surfaces, while also allowing the highlighting and evaluation of the individual contributions of the substrate and coating film to the global effect. Two types of wood test samples: V1 (uncoated) and V2 (coated) and coating films on 1mm thick clear glass slides were employed. The behaviour of the wood substrate under the coating film was simulated on uncoated substrate covered with a coated glass slide. European maple (Acer pseudoplatanus L.) and two types of transparent water-based varnishes with 2k formulations were used. The samples were exposed for up to 72 hours to artificial UV-VIS light in accelerated tests simulating natural light passing through window glass. Colour changes were measured in the CIELab system, as well as the chemical changes of the wood substrate and the coating films by FTIR analysis. Exposure of uncoated maple wood resulted in a total colour difference (E) of 10.83 units and this was only slightly reduced by coating (9.29-9.81 units). Exposure through the glass slide reduced the colour changes of the uncoated and coated wood surfaces by 37-43%. Colour changes of 5.79-6.85 units were measured on the wood substrate exposed under coated glass slides, whilst the colour changes of the coating films on glass slides were only 0.64-1.0 units, which indicates a maximum contribution of the wood substrate to the light-induced colour changes of the coated surfaces. FTIR investigation confirmed this finding.
评估木材基材和涂膜对木材表面光诱导颜色变化影响的实验方法
本文介绍了一种独创的实验室方法,用于确定和比较未涂层和涂层木材表面的光诱导颜色变化,同时还可以突出和评估基材和涂膜对整体效果的各自贡献。两种木材测试样本:使用的是 V1(未涂覆)和 V2(涂覆)以及涂覆在 1 毫米厚透明玻璃载玻片上的薄膜。在涂有涂层的玻璃载玻片上覆盖未涂涂层的基材,模拟涂膜下木材基材的行为。使用了欧洲枫木(Acer pseudoplatanus L.)和两种 2k 配方的透明水性清漆。在模拟自然光穿过窗玻璃的加速测试中,样品在人工紫外可见光下暴露长达 72 小时。在 CIELab 系统中测量了颜色变化,并通过傅立叶变换红外分析法测量了木材基材和涂膜的化学变化。未经涂层的枫木在曝晒后的总色差 (E) 为 10.83 个单位,而涂层仅略微减少了这一色差(9.29-9.81 个单位)。通过玻璃载玻片进行曝光可使未涂层和涂层木材表面的色差减少 37-43%。在涂有涂层的玻璃载玻片下曝光的木质基材测得的颜色变化为 5.79-6.85 个单位,而玻璃载玻片上的涂层薄膜的颜色变化仅为 0.64-1.0 个单位,这表明木质基材对涂层表面由光引起的颜色变化的贡献最大。傅立叶变换红外光谱研究证实了这一结论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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