A Study on the Role of Clay Nanoparticles and Temperature on the Creep Behavior of Polyethylene Matrix Nanocomposite

Mostafa Abbaszadeh Valojerdi, S. M. Zebarjad, M. H. Moghim
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Abstract

Objective: In the current research, the creep behavior of polyethylene (PE) matrix nanocomposites reinforced with different content of clay nano particles (i.e., 0, 1, 3, 5, 10wt%) at different temperatures (25 and 50℃) has been investigated. Methods: In order to produce composite samples of pure PE reinforced with different percentages of clay (0, 1, 3, 5 and 10% by weight), a twin extruder was used in the temperature range of 200-230℃. Also, to produce the standard samples, an injection machine was used using in the temperature range of 220-230℃. The samples were subjected to a constant load, typically around 0.7 to 0.8 times the yield strength, at 25 and 50℃ , and at constant strain rate of 0.1min-1. Results: The creep investigations showed that for PE and its nanocomposites the creep trend could be divided into primary, secondary, and tertiary stages. The length of each stage depended strongly on both temperature and the stress level at which the samples tested as well as the clay content. It was observed that adding nano particles in small amounts (1wt%) led to an increase in the length of the creep life of PE and it also improved this property in both temperatures. Conclusion: It was observed that increasing test temperature from causes to decrease the creep strength as well as a rapid onset of plastic deformation for all materials including PE and its nanocomposites. PE nanocomposites with higher than 1wt% clay exhibited a noticeable drop in creep strength particularly at 50℃.
粘土纳米颗粒和温度对聚乙烯基质纳米复合材料蠕变行为的影响研究
研究目的在当前的研究中,研究了不同含量的粘土纳米颗粒(即 0、1、3、5、10wt%)增强的聚乙烯(PE)基纳米复合材料在不同温度(25 和 50℃)下的蠕变行为。研究方法为了生产纯聚乙烯与不同比例粘土(0、1、3、5 和 10%(重量百分比))增强的复合材料样品,使用了双挤压机,温度范围为 200-230℃。此外,为了生产标准样品,还使用了注塑机,温度范围为 220-230℃。样品在 25 和 50℃的温度下,以 0.1 分钟-1 的恒定应变速率承受恒定载荷,通常约为屈服强度的 0.7 至 0.8 倍。结果:蠕变研究表明,聚乙烯及其纳米复合材料的蠕变趋势可分为初级、中级和高级阶段。每个阶段的长短在很大程度上取决于测试样品的温度和应力水平以及粘土含量。据观察,添加少量(1wt%)纳米颗粒可延长聚乙烯的蠕变寿命,而且在两种温度下都能改善这一特性。结论据观察,试验温度升高会导致蠕变强度降低,并使所有材料(包括聚乙烯及其纳米复合材料)的塑性变形迅速开始。粘土含量高于 1wt% 的聚乙烯纳米复合材料的蠕变强度明显下降,尤其是在 50℃时。
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