Mechanical, thermal, and morphological properties of poly(lactic acid) (PLA)/ recycled tyre rubber waste compatibilised with chain extender

Abstract

The accumulation of waste tires in our society is a pressing issue due to their short lifespan and increasing demand. This research delves into effective methods for recycling waste tires, with a particular focus on utilizing biopolymers. Polylactic acid (PLA), a completely biodegradable polymer, has gained popularity for its biocompatibility, biodegradability, mechanical strength, and ease of processing. To overcome its toughness and thermal stability limitations, PLA has been blended with commercial polymers, such as rubber. Furthermore, the incorporation of recycled tire waste into PLA has demonstrated the potential to enhance its durability and strength. Joncryl® ADR is used as a chain extender and reactive compatibilizer to enhance the chemical interactions in the binary blend. The samples were prepared using a twin-screw extruder with the temperature between 150 and 190 ºC and 60 rpm of screw speed. These blends are then analyzed using a range of characterization techniques, including Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), tensile testing, and notched Izod impact testing. The blends were then characterized by chemical changes, thermal transitions, and thermal degradation. it was found that the 90/10/0.6 (PLA/RW/ADR) nanocomposite exhibited maximum thermal degradation.