Studies on Aging Behavior and Degradation Mechanism of Raw EPDM Rubber Under γ-Ray Irradiation

Xin-yi Du, Sheng-nan Jiang, Zhao Qing, Meng-yuan Zhu, Hong-zhen Wang, Cun-guo Wang, Ai-hua He, Ye Xin, Zhao Bo
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Abstract

The aging behavior and mechanism of EPDM rubber were investigated by conducting different doses of γ-rays irradiation in raw EPDM rubber. A series of characterization methods such as Mooney viscosity, molecular weight and its distribution, rubber processing analysis, infrared spectroscopy analysis et al. were carried out. Structure and modifications of the raw EPDM rubber were tested under different irradiation doses. The results showed that the Mooney viscosity and molecular weight of EPDM rubber showed a significant decrease with increasing irradiation dose. The gel content and glass transition temperature increased gradually. As strain rose, the energy storage modulus diminished. The loss factor decreased at first and then increased with increasing strain during irradiation aging.
生三元乙丙橡胶在 γ 射线辐照下的老化行为和降解机理研究
通过对三元乙丙橡胶生料进行不同剂量的γ射线辐照,研究了三元乙丙橡胶的老化行为和机理。进行了一系列表征方法,如门尼粘度、分子量及其分布、橡胶加工分析、红外光谱分析等。在不同的辐照剂量下,对三元乙丙橡胶原料的结构和改性进行了测试。结果表明,随着辐照剂量的增加,三元乙丙橡胶的门尼粘度和分子量显著下降。凝胶含量和玻璃化温度逐渐升高。随着应变的增加,储能模量减小。在辐照老化过程中,随着应变的增加,损耗因子先降低后升高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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