Insights into carbon dioxide sequestration into coal seams through coupled gas flow-adsorption-deformation modelling

Abstract

Injecting carbon dioxide (CO₂) into coal seams may unlock substantial carbon sequestration potential. Since the coal acts like a carbon filter, it can preferentially absorb significant amounts of CO₂. To explore this further, desorption of the adsorbed gas due to pressure drop is investigated in this paper, to achieve an improved understanding of the long-term fate of injected CO₂ during post-injection period. This paper presents a dual porosity model coupling gas flow, adsorption and geomechanics for studying coupled processes and effectiveness of CO₂ sequestration in coals. A new adsorption−desorption model derived based on thermodynamics is incorporated, particularly, the desorption hysteresis is considered. The reliability of the proposed adsorption-desorption isotherm is examined via validation tests. It is indicated that occurrence of desorption hysteresis is attributed to the adsorption-induced pore deformation. After injection ceases, the injected gas continues to propagate further from the injection well, while the pressure in the vicinity of the injection well experiences a significant drop. Although the adsorbed gas near the well also decreases, this decrease is less compared to that in pressure because of desorption hysteresis. The unceasing spread of CO₂ and drops of pressure and adsorbed gas depend on the degree of desorption hysteresis and heterogeneity of coals, which should be considered when designing CO₂ sequestration into coal seams.