Recent Advances of Covalent Organic Frameworks as Water Splitting Electrocatalysts

Y. Yusran, Jie Zhao, Fengqian Chen, Q. Fang
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Abstract

Developing high performance, durable, yet low-lost catalyst for electrocatalytic water splitting technology has been a research priority to tackle the global energy crisis. In this regard, covalent organic frameworks (COFs) have received numerous attentions as promising water splitting electrocatalysts as they can provide an excellent platform for settlement of electrocatalytic active site, high porosity, and good stability. In this review, recent advance on the design and application of COFs for water electrolysis, that are hydrogen and oxygen evolution reaction (HER and OER) electrocatalysts are briefly discussed. Among them, both noble and non-noble metals containing COFs as well as metal-free COFs based electrocatalysts are elaborated. Furthermore, a brief perspective on development of COFs in the field of water splitting electrocatalysis is provided.

Abstract Image

共价有机框架作为水分离电催化剂的最新进展
为电催化水分解技术开发高性能、耐用、低损耗的催化剂已成为解决全球能源危机的研究重点。在这方面,共价有机骨架(COFs)因其具有良好的电催化活性位点沉降平台、高孔隙率和良好的稳定性而受到广泛关注。本文综述了国内外电解用COFs(氢析氧反应和OER)电催化剂的设计和应用进展。其中,阐述了含贵金属和非贵金属COFs以及无金属COFs基电催化剂。最后,对COFs在水分解电催化领域的发展作了简要展望。
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CiteScore
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