Xuemei Ouyang , Xu Zhao , Che He , Fucheng Yin , Xinming Wang , Jingxian Hu
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引用次数: 0
Abstract
The phase equilibria of the Co–Zn–Zr ternary system were systematically studied by combining experimental analysis and thermodynamic modelling. The 450 °C isothermal section at the Zn-rich corner and the 600 °C isothermal section of Co–Zn–Zr system were studied by means of scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. Seventeen and ten three-phase regions were obtained at 600 and 450 °C isothermal sections, respectively. Three stable ternary compounds named τ1 (ZrCo2Zn20), τ2 (Zr5Co3Zn12) and τ3 (Zr10Co3Zn7) were found in the 600 °C isothermal section. Among them, the Bravais lattice symmetry of the τ2 phase is a simple tetragonal lattice, and its lattice parameters are a = 8.945 Å, b = 8.945 Å, c = 11.737 Å and α = β = γ = 90°. Based on the comprehensive evaluation of the current experimental results and the data reported in the literature, the thermodynamic description of the system was developed using the CALPHAD technique. A set of self-consistent thermodynamic parameters for the Co–Zn–Zr ternary system was obtained with good agreement between the experimental and calculated results.
期刊介绍:
The design of industrial processes requires reliable thermodynamic data. CALPHAD (Computer Coupling of Phase Diagrams and Thermochemistry) aims to promote computational thermodynamics through development of models to represent thermodynamic properties for various phases which permit prediction of properties of multicomponent systems from those of binary and ternary subsystems, critical assessment of data and their incorporation into self-consistent databases, development of software to optimize and derive thermodynamic parameters and the development and use of databanks for calculations to improve understanding of various industrial and technological processes. This work is disseminated through the CALPHAD journal and its annual conference.