Marie Romedenne, Rishi Pillai, Sebastien Dryepondt, Bruce A. Pint
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引用次数: 0
Abstract
Abstract Hydrogen-fueled microturbines are being considered as part of the future green microgrid. However, the use of hydrogen as a fuel presents new challenges for selection and development of suitable high temperature materials for hydrogen combustion. The burning of hydrogen is expected to result in higher operating temperatures and higher than typically observed water vapor contents in exhaust gases versus burning natural gas. In the present work, foil specimens of various Fe- and Ni-based alloys were oxidized in air + 10 % H2O and air + 60% H2O for up to 5,000 h at 700 °C to simulate the exhaust atmosphere of natural gas and hydrogen-fueled microturbines. The impact of alloy composition and water vapor content on the oxidation/ volatilization induced loss of wall thickness was experimentally evaluated. Enhanced external oxidation and volatilization of Cr2O3 and Ti-doped Cr2O3 scales was observed in air + 60% H2O compared to air + 10% H2O. No significant impact of the higher water vapor content was observed on Al2O3 scales formed on Fe-based alumina forming alloys. Lifetime modeling was employed to predict the combined effects of water vapor content, gas flow rates, temperature and alloy composition on the oxidation-induced lifetime of the investigated materials.
期刊介绍:
The ASME Journal of Engineering for Gas Turbines and Power publishes archival-quality papers in the areas of gas and steam turbine technology, nuclear engineering, internal combustion engines, and fossil power generation. It covers a broad spectrum of practical topics of interest to industry. Subject areas covered include: thermodynamics; fluid mechanics; heat transfer; and modeling; propulsion and power generation components and systems; combustion, fuels, and emissions; nuclear reactor systems and components; thermal hydraulics; heat exchangers; nuclear fuel technology and waste management; I. C. engines for marine, rail, and power generation; steam and hydro power generation; advanced cycles for fossil energy generation; pollution control and environmental effects.