Associative ionization in collisions of H++H− and H(1 Physical Review Pub Date : 2023-11-13 DOI:10.1103/physreva.108.052811 Johan Hörnquist, Patrik Hedvall, Ann E. Orel, Åsa Larson 求助PDF {"title":"Associative ionization in collisions of H++H− and H(1<mml:mi…","authors":"Johan Hörnquist, Patrik Hedvall, Ann E. Orel, Åsa Larson","doi":"10.1103/physreva.108.052811","DOIUrl":null,"url":null,"abstract":"Associative ionization in collisions of ${\\mathrm{H}}^{+}+{\\mathrm{H}}^{\\ensuremath{-}}$ as well as $\\mathrm{H}(1s)+\\mathrm{H}(ns)$ with $n=2,3,4$ is studied theoretically. Relevant adiabatic potential curves and nonadiabatic couplings are calculated ab initio and the autoionization from the lowest electronic resonant states in the ${}^{1}{\\mathrm{\\ensuremath{\\Sigma}}}_{g/u}^{+}$ and ${}^{3}{\\mathrm{\\ensuremath{\\Sigma}}}_{g/u}^{+}$ symmetries are considered. The cross sections are obtained by solving the coupled Schr\\\"odinger equation, including a complex potential matrix, in a strict diabatic representation. The importance of using a nonlocal description of autoionization is investigated. Associative ionization is also studied for different isotopes of hydrogen. Calculated cross sections are compared with results from measurements.","PeriodicalId":20121,"journal":{"name":"Physical Review","volume":"11 6","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Review","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1103/physreva.108.052811","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0} 引用次数: 0 引用 批量引用 Abstract Associative ionization in collisions of ${\mathrm{H}}^{+}+{\mathrm{H}}^{\ensuremath{-}}$ as well as $\mathrm{H}(1s)+\mathrm{H}(ns)$ with $n=2,3,4$ is studied theoretically. Relevant adiabatic potential curves and nonadiabatic couplings are calculated ab initio and the autoionization from the lowest electronic resonant states in the ${}^{1}{\mathrm{\ensuremath{\Sigma}}}_{g/u}^{+}$ and ${}^{3}{\mathrm{\ensuremath{\Sigma}}}_{g/u}^{+}$ symmetries are considered. The cross sections are obtained by solving the coupled Schr\"odinger equation, including a complex potential matrix, in a strict diabatic representation. The importance of using a nonlocal description of autoionization is investigated. Associative ionization is also studied for different isotopes of hydrogen. Calculated cross sections are compared with results from measurements. 分享 查看原文 本刊更多论文 H++H -和H(1 从理论上研究了${\ mathm {H}}^{+}+{\ mathm {H}}^{\ensuremath{-}}$和$\ mathm {H}(1s)+\ mathm {H}(ns)$与$n=2,3,4$碰撞时的结合电离。从头计算了相关的绝热势曲线和非绝热耦合，并考虑了${}^{1}{\ mathm {\ensuremath{\Sigma}} _{g/u}^{+}$和${}}^{3}{\ mathm {\ensuremath{\Sigma}} _{g/u}^{+}$对称性中最低电子共振态的自电离。通过求解包含复势矩阵的耦合Schr\ odinger方程，得到了严格非绝热表示的截面。研究了使用非局域自离描述的重要性。还研究了氢的不同同位素的缔合电离。计算截面与实测结果进行了比较。 本文章由计算机程序翻译，如有差异，请以英文原文为准。 求助全文 约1分钟内获得全文 求助全文 来源期刊 Physical Review 自引率 0.00% 发文量 0 相关文献 × 引用 GB/T 7714-2015 复制 MLA 复制 APA 复制 导出至 BibTeX EndNote RefMan NoteFirst NoteExpress × 求助内容： 期刊论文 学位论文 图书 其他 (专利、报告等) 只需要正文 仅需补充材料 应助结果提醒方式： 微信（请自行确认已关注Book学术公众号） 邮件 保存 保存后同步修改账户信息中的邮箱 确认发布求助 × 处理提示 您的部分求助已有人上传文件，您还尚未处理，请先处理完毕再发起新的求助 点击查看 × 努力提交中 提交成功 继续求助查看详情 × 提示 您的信息不完整，为了账户安全，请先补充。 现在去补充 × 没积分了 多种获得积分方式，供你选择！ 查看如何获取积分 × 提示 您因"违规操作" 具体请查看互助需知 我知道了 × 提示 现在去查看 取消 × 提示 确定 × 快捷登录 密码登录 用户名： 密码： 验证码： 两周内记住我 忘记密码？ 手机号： 验证码： 没有帐号？现在注册 请完成安全验证× 微信好友 朋友圈 QQ好友 复制链接 取消 已复制链接 快去分享给好友吧! 我知道了 点击右上角分享 0 $(function () { var title = $("#title").val(); var id = $("#id").val(); $.post("/Literature/GetRelatedLiterature", { id: id, title: title }, function (result) { if (result != null) { var html = ``; for (var i = 0; i < result.length; i++) { html += `<div class="sslist">`; html += `<a class="caption" href="` + $("#url1").val() + result[i].ArticleID + `.htm">` + result[i].Title + `</a>`; html += ` <div class="substance">`; html += `<span class="IF">IF ` + result[i].PeriodicalIF + ` </span>`; if (result[i].RegionNum > 0) { html += `<span class="fq` + result[i].RegionNum + `">` + result[i].RegionNum + `区 ` + result[i].RegionCategory + `</span>`; } //var EmployDataBaseShoreName = result[i].EmployDataBaseShoreName; //if (EmployDataBaseShoreName != "" && EmployDataBaseShoreName!=null) { // var names = EmployDataBaseShoreName.split('||') // for (var j = 0; j < names.length; j++) { // html += `<span class="fq5">` + names[j] + `</span>`; // } //} //html += ``; html += `</div>`; html += `<div class="substance">`; html += `<a href="` + $("#url2").val() + "_d" + result[i].PeriodicalID + `.htm" target="_blank">` + result[i].PeriodicalName + `</a>`; html += `<span class="Pub">Pub Date : ` + result[i].PublishDate + `</span>`; html += `</div>`; html += ` <div class="author">`; html += result[i].AuthorName; html += `</div>`; html += `</div>`; } if (html.length > 0) { $("#xglist").show(); $("#xglist").append(html); } } }); getReferenceCount(); }); function getReferenceCount() { var LocalId = localStorage.getItem("referenceName"); if (LocalId != null) { $.get("/Literature/GetBatchReferenceCountByLocalId", { LocalId: LocalId }, function (result) { $("#referencecount").html(result.Code); }, "json"); } else { $("#referencecount").html('0'); } } wx.config({ debug: false, appId: 'wx999b2eb01732df2e', timestamp: '1732872733', nonceStr: 'YdyUvVn5zIoPyTzG', signature: 'd43549141aa4821e679fd734079a83c8557d0938', jsApiList: [ 'onMenuShareTimeline', 'onMenuShareAppMessage', 'hideMenuItems' ] });

Abstract

Associative ionization in collisions of ${\mathrm{H}}^{+}+{\mathrm{H}}^{\ensuremath{-}}$ as well as $\mathrm{H}(1s)+\mathrm{H}(ns)$ with $n=2,3,4$ is studied theoretically. Relevant adiabatic potential curves and nonadiabatic couplings are calculated ab initio and the autoionization from the lowest electronic resonant states in the ${}^{1}{\mathrm{\ensuremath{\Sigma}}}_{g/u}^{+}$ and ${}^{3}{\mathrm{\ensuremath{\Sigma}}}_{g/u}^{+}$ symmetries are considered. The cross sections are obtained by solving the coupled Schr\"odinger equation, including a complex potential matrix, in a strict diabatic representation. The importance of using a nonlocal description of autoionization is investigated. Associative ionization is also studied for different isotopes of hydrogen. Calculated cross sections are compared with results from measurements.