Photocatalytic degradation of methylene blue dye using synthesized CoxNi1-xFe2O4 nanoparticles under direct visible light

Seemab Hussnain, Syed Salman Ali, Muhammad Qadeer Alam, Muhammad Hamad Safder, Atia Roman, Tehreem Fatima, Muhammad Asif
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Abstract

A cobalt doped nickel ferrites were prepared in this study. Photo catalysts made of cobalt-doped nickel ferromagnetic materials nanoparticles were utilized to degrade dyes. These nanoparticles were synthesized by the co-precipitation technique. A UV-Vis spectrophotometer was used to determine the band gap. These ferrites had band gap between 2.32eV to 2.20eV. The spinel structure of ferrites was characterized X-ray diffraction (XRD) technique. The shape and average size of synthesized nanoparticles was determined by scanning electron microscopy (SEM). Fourier transform infrared FTIR shows metal-oxygen bond in the range of 400-1000cm-1. The photocatalytic degradation of dye under UV radiation and direct sunlight was studied. Almost 72 to 92 percent methylene blue dye was degraded in first 100 mints owing to the active octahedral to tetrahedral lattice sites and prevent the recombination of electron/hole pair. The photo-degradation of methylene blue (MB) and a few textile dyes was practised to examine the photocatalytic performance of Co-NiFe2O4. It was observed as the most effective photocatalyst for treating sewage.
直接可见光下合成CoxNi1-xFe2O4纳米颗粒光催化降解亚甲基蓝染料
本研究制备了一种钴掺杂镍铁氧体。采用纳米钴掺杂镍铁磁材料制备光催化剂降解染料。采用共沉淀法合成了这些纳米颗粒。用紫外可见分光光度计测定带隙。这些铁氧体的带隙在2.32 ~ 2.20eV之间。采用x射线衍射(XRD)技术对铁素体尖晶石结构进行了表征。利用扫描电子显微镜(SEM)测定了合成的纳米颗粒的形状和平均尺寸。傅里叶变换红外FTIR显示金属-氧键在400-1000cm-1范围内。研究了紫外辐射和阳光直射下染料的光催化降解。由于活跃的八面体到四面体的晶格位置和阻止电子/空穴对的重组,亚甲基蓝染料在前100分钟降解率约为72% ~ 92%。通过对亚甲基蓝(MB)和几种纺织染料的光降解实验,考察了Co-NiFe2O4的光催化性能。它是处理污水最有效的光催化剂。
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