A Study on the Physical, Optical and Radiation Shielding Capabilities of Phosphate Zinc Telluride Glasses as a Result of ZnO/In2O3 Translocation

Erkan İLİK
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Abstract

New In2O3-doped phosphate zinc tellurite glasses synthesized using melt-quenching method were investigated. It was observed that the synthesized glasses exhibit transparent properties. Densities of synthesized glasses changed significantly related to the doping ratio of In2O3. This implies that radiation shielding abilities can be enhanced. In other respects, the almost linear elevation in molar volume values indicated that the glass network expanded as a result of the ZnO/In2O3 translocation. As the additive ratio increases, the optical band gap value increases from 2.96 eV to 3.47 eV, while the Urbach energies decrease from 0.350 eV to 0.180 eV. In2O3 contribution has a regulatory effect on the structure of phosphate zinc tellurite glasses. In phosphate zinc tellurite glasses evaluated in terms of radiation shielding properties, it was observed that the In2O3 additive contributed significantly to the shielding properties and the glass with the best radiation shielding was 6 mol% In2O3 doped glass. It is obvious that by raising the density values of the produced glasses, the ZnO/In2O3 translocation in phosphate zinc tellurite glasses enhanced their radiation shielding properties.
ZnO/In2O3易位对磷酸碲化锌玻璃物理、光学和辐射屏蔽性能的影响
采用熔融淬火法制备了新型掺in2o3磷酸盐碲酸锌玻璃。观察到合成的玻璃具有透明的性质。合成玻璃的密度随In2O3掺杂比的变化而发生显著变化。这意味着可以增强辐射屏蔽能力。在其他方面,摩尔体积值几乎呈线性上升表明,玻璃网络的扩大是ZnO/In2O3易位的结果。随着添加比的增加,光学带隙值从2.96 eV增加到3.47 eV,而乌尔巴赫能从0.350 eV降低到0.180 eV。In2O3的加入对磷酸碲酸锌玻璃的结构有调节作用。在对磷碲酸锌玻璃进行辐射屏蔽性能评价时,发现In2O3添加剂对屏蔽性能有显著影响,其中6 mol% In2O3掺杂玻璃的屏蔽性能最好。结果表明,通过提高玻璃的密度值,ZnO/In2O3在磷酸碲酸锌玻璃中的易位提高了玻璃的辐射屏蔽性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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