{"title":"Statistical dynamics of a hard sphere gas: fluctuating Boltzmann equation and large deviations","authors":"Thierry Bodineau, Isabelle Gallagher, Laure Saint-Raymond, Sergio Simonella","doi":"10.4007/annals.2023.198.3.3","DOIUrl":null,"url":null,"abstract":"We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square root of the average number of particles, converge to a Gaussian process driven by the fluctuating Boltzmann equation, as predicted by Spohn; (2) large deviations are exponentially small in the average number of particles and are characterized, under regularity assumptions, by a large deviation functional as previously obtained by Rezakhanlou for dynamics with stochastic collisions. The results are valid away from thermal equilibrium, but only for short times. Our strategy is based on uniform a priori bounds on the cumulant generating function, characterizing the fine structure of the small correlations.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":null,"pages":null},"PeriodicalIF":8.3000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"25","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4007/annals.2023.198.3.3","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 25
Abstract
We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square root of the average number of particles, converge to a Gaussian process driven by the fluctuating Boltzmann equation, as predicted by Spohn; (2) large deviations are exponentially small in the average number of particles and are characterized, under regularity assumptions, by a large deviation functional as previously obtained by Rezakhanlou for dynamics with stochastic collisions. The results are valid away from thermal equilibrium, but only for short times. Our strategy is based on uniform a priori bounds on the cumulant generating function, characterizing the fine structure of the small correlations.
期刊介绍:
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.