{"title":"Ground state properties in the quasiclassical regime","authors":"Michele Correggi, Marco Falconi, Marco Olivieri","doi":"10.2140/apde.2023.16.1745","DOIUrl":null,"url":null,"abstract":"We study the ground state energy and ground states of systems coupling non-relativistic quantum particles and force-carrying Bose fields, such as radiation, in the quasi-classical approximation. The latter is very useful whenever the force-carrying field has a very large number of excitations,and thus behaves in a semiclassical way, while the non-relativistic particles, on the other hand, retain their microscopic features. We prove that the ground state energy of the fully microscopic model converges to the one of a nonlinear quasi-classical functional depending on both the particles' wave function and the classical configuration of the field. Equivalently, this energy can be interpreted as the lowest energy of a Pekar-like functional with an effective nonlinear interaction for the particles only. If the particles are confined, the ground state of the microscopic system converges as well, to a probability measure concentrated on the set of minimizers of the quasi-classical energy.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2140/apde.2023.16.1745","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 9
Abstract
We study the ground state energy and ground states of systems coupling non-relativistic quantum particles and force-carrying Bose fields, such as radiation, in the quasi-classical approximation. The latter is very useful whenever the force-carrying field has a very large number of excitations,and thus behaves in a semiclassical way, while the non-relativistic particles, on the other hand, retain their microscopic features. We prove that the ground state energy of the fully microscopic model converges to the one of a nonlinear quasi-classical functional depending on both the particles' wave function and the classical configuration of the field. Equivalently, this energy can be interpreted as the lowest energy of a Pekar-like functional with an effective nonlinear interaction for the particles only. If the particles are confined, the ground state of the microscopic system converges as well, to a probability measure concentrated on the set of minimizers of the quasi-classical energy.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.