New substituted pentazadienes as initiators of free-radical polymerization: synthesis, photochemical properties and perspectives for holographic media

Abstract

AbstractThe series of 4,4′-substituted 3-hydroxyethyl-pentaza-1,4-dienes were synthesized in the reaction of aromatic diazonium salts with an ethanol amine. Photolysis of pentaza-1,4-dienes was investigated by means of UV/Vis spectroscopy. Electron donating methyl and methoxy substituents were found to increase photosensitivity whereas electron withdrawing chloro-substituents cause higher photolytic stability. 3-hydroxyethyl-pentaza-1,4-dienes as a radical polymerization initiator has been successfully investigated in 10% methyl methacrylate solution in DMF. Gel permeation chromatography (GPC) and differential scanning calorimetry (DSC) were used for obtained polymers characteristics evaluation. The highest values of PMMA Mn and Đ can be obtained in the case of chloro-substituted derivative. The holograms of a plane wavefront were recorded in media based on obtained PMMA doped by azo-dye by a 532 nm laser in a ∼1-μm-thick sample. The diffraction efficiency values for parallel polarized acting light increased in Cl→Me→OMe series.Keywords: Azo dyesholographydiffraction efficiencyPMMAradical polymerization initiator Disclosure statementThere are no conflicts to declare.