A Challenge

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2023-10-02 DOI:10.29356/jmcs.v67i4.2077

R. Daniel Little

引用次数: 0

Abstract

The present contribution overviews several aspects of my groups’ involvement in the field of mediated electron transfer. From the laboratories of its pioneers to the present day, the field maintains a position of interest and fundamental importance, and is now widely accepted and utilized. I begin with a brief review of the basics where we will: differentiate mediated and direct electrolysis; highlight similarities between it and sensitized photolyses; explore the steps/stages associated with a mediated process focusing particularly upon the kinetics and thermodynamics of the electron transfer step; describe how to overcome the thermodynamic impasse that frequently accompanies electron transfer.

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一个挑战

目前的贡献概述了我的小组在介导电子转移领域参与的几个方面。从其先驱的实验室到今天，这一领域一直保持着人们的兴趣和根本重要性，现在已被广泛接受和利用。我首先简要回顾一下基础知识，我们将: & # x0D;区分间接电解和直接电解; 强调它与敏化光解的相似性; 探索与中介过程相关的步骤/阶段，特别关注电子转移步骤的动力学和热力学; 描述如何克服经常伴随着电子转移的热力学僵局。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.