Numerical study on three-stage ignition of dimethyl ether by hot air under engine-relevant conditions

Abstract

AbstractNon-premixed combustion often occurs in practical engines, and it is affected by the coupling effects of chemical kinetics and transport. This study aims to elucidate the individual effect of chemical kinetics, molecular diffusion, and convective transport on non-premixed combustion. To this end, three types of reactive systems are investigated by numerical simulations considering detailed chemistry and transport: (1) thermochemical system: 0D homogeneous autoignition, (2) thermochemical-diffusive system: 1D non-premixed ignition in a static diffusion layer, (3) thermochemical-diffusive-convective system: 1D non-premixed ignition in a counterflow and 2D lifted flame in a coflow. The simulations are carried out for diluted dimethyl ether and hot air under engine-relevant conditions with a pressure of 40 atm and hot air temperatures of 700∼1500 K. First, homogeneous ignition process of DME/air premixture is investigated. It is found that, apart from the low- and high-temperature chemistry which are essential in the typical two-stage ignition, the intermediate-temperature chemistry can also play an important role, especially for slow reaction process in fuel rich regions. Then, the effects of thermochemical conditions and molecular diffusion are assessed for non-premixed ignition process in the 1D diffusion layer. The results show that, the reaction front always initiates from local autoignition in most reactive regions; then it propagates either in sequential auto-ignition mode or in diffusion-driven mode as a deflagration wave. With various thermochemical conditions, the chemical kinetics behave differently and produce complex multibrachial (tetrabrachial, pentabrachial and hexbrachial) structures during the reaction front propagation. Decreasing the diffusion layer thickness generally delays the reaction front initiation but enhances its transition into a diffusion-driven flame. Finally, it is shown that 1D diffusion layer simulations can qualitatively reproduce the complex multibrachial structures in 1D counterflow and 2D coflow at certain conditions. A regime diagram is proposed to separate the effects of chemical kinetics, molecular diffusion, and convective transport.Keywords: non-premixed combustiondimethyl etherthree-stage ignitionintermediate-temperature chemistry Disclosure statementNo potential conflict of interest was reported by the author(s).Supplemental dataSupplemental data for this article can be accessed here https://doi.org/10.1080/13647830.2023.2261423.Additional informationFundingThis work is jointly supported by the National Natural Science Foundation of China (Nos. 52176096 and 51861135309) and the German Research Foundation (DFG, no. 411275182).