Influence mechanism of dispersion and agglomeration characteristics of micron/nano carbon dust on its combustion kinetics and explosion process

IF 2.1 4区 材料科学 Q3 CHEMISTRY, PHYSICAL
Jie Mu, Qifu Bao, Shenghua Wang, Jianmiao Zhu, Xuesheng Li, Bo Jia, Xuefan Chen, Taosong Liu
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引用次数: 0

Abstract

AbstractDue to the widespread use of lithium-ion batteries, evaluations of the flammability and explosive characteristics of carbon dust materials as anodes require attention. Carbon dust often reaches the micron/nano scale, and dust particle state and explosion risk generated in different industrial scenarios are different, which is in urgent need of research. Nanoscale dust has relatively static coagulation properties and shows characteristics of dispersion and reagglomeration under a certain airflow. The particle size characteristics affect its thermodynamic characteristics and various consequence parameters of dust explosion. The oxidation and combustion characteristics are mainly affected by dust particle size distribution characteristics. The apparent activation energy is mainly affected by the proportion of small and medium-sized particles and pre-exponential index factor is mainly affected by the dust overall average particle size and specific surface area. The explosion consequence parameters are affected by the thermodynamic parameters, by the disturbance state, particle distribution degree of dust cloud and other factors, which affect the heat radiation and heat transfer process to some extent resulting in different explosion consequence parameters. Due to the agglomeration characteristics of nano-level dust, the minimum ignition energy and minimum ignition temperature of nano-level dust are generally smaller than that of micron level dust.Keywords: Carbon dustparticle characteristicsthermodynamic parameterexplosion parametersdispersion and agglomeration AcknowledgmentsThe authors gratefully acknowledge the financial support from the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China, the “Pioneer” and “Leading Goose” R&D Program of Zhejiang, Key Laboratory of Safety Engineering and Technology Research of Zhejiang Province, the Key Research and Development Program of Zhejiang Province and the Public Projects of Zhejiang Province of China .CRediT authorship contribution statementJie Mu: Conceptualization, Funding acquisition, Writing-original draft. Qifu Bao: Writing-review & editing. Shenghua Wang: Conceptualization, Data curation. Xuesheng Li: Resources, Data processing. Jianmiao Zhu: Investigation, Formal analysis. Bo Jia: Project administration, Supervision, Review & editing. Xuefan Chen: Data test. Taosong Liu: Validation, Visualization.Disclosure statementThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this article.Additional informationFundingThis work was supported by the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China (NO. LQQ20E040001), the “Pioneer” and “Leading Goose” R&D Program of Zhejiang (NO. 2022C03162), Key Laboratory of Safety Engineering and Technology Research of Zhejiang Province (No. 202207), the Key Research and Development Program of Zhejiang Province (NO. 2021C03151) and the Public Projects of Zhejiang Province of China (NO. LGG21G010001).
微米/纳米碳粉的分散和团聚特性对其燃烧动力学和爆炸过程的影响机理
摘要随着锂离子电池的广泛应用,碳尘材料作为阳极材料的可燃性和易爆性评价值得重视。碳尘往往达到微米/纳米尺度,不同工业场景下产生的粉尘颗粒状态和爆炸危险性不同,急需研究。纳米级粉尘具有相对静态的混凝特性,在一定气流下表现出分散和再团聚的特性。粉尘粒度特性影响其热力学特性和粉尘爆炸的各种后果参数。粉尘的氧化和燃烧特性主要受粉尘粒径分布特性的影响。表观活化能主要受中小颗粒比例的影响,指前指数因子主要受粉尘总体平均粒径和比表面积的影响。爆炸后果参数受热力参数、扰动状态、粉尘云颗粒分布程度等因素的影响,在一定程度上影响热辐射和换热过程,导致爆炸后果参数不同。由于纳米级粉尘的团聚特性,纳米级粉尘的最小点火能量和最小点火温度一般小于微米级粉尘。关键词:本文作者感谢浙江省自然科学基金联合基金、浙江省“先行者”和“领雁”研发计划、浙江省安全工程与技术研究重点实验室、浙江省重点研发计划项目及浙江省公共工程项目。署名声明穆杰:立项,获资助,撰写-原稿。鲍启富:写作、评审、编辑。王盛华:概念化,数据策展。李学生:资源,数据处理。朱建淼:调查,形式分析。博佳:项目管理、监督、评审、编辑。陈雪凡:数据检验。刘涛松:验证,可视化。披露声明作者声明,他们没有已知的竞争经济利益或个人关系,可能会影响本文所报道的工作。项目资助:浙江省自然科学基金项目(NO. 5);项目编号:LQQ20E040001),浙江省“先行者”、“领头鹅”科技发展计划项目(NO. qq20e040001);2022C03162),浙江省安全工程与技术研究重点实验室(No. 202207),浙江省重点研发计划项目(No. 2022C03162);项目资助:2021C03151)和浙江省公共工程项目(NO. 2021C03151);LGG21G010001)。
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来源期刊
Fullerenes, Nanotubes and Carbon Nanostructures
Fullerenes, Nanotubes and Carbon Nanostructures 工程技术-材料科学:综合
CiteScore
4.80
自引率
17.40%
发文量
85
审稿时长
1 months
期刊介绍: The international and interdisciplinary forum, Fullerenes, Nanotubes, and Carbon Nanostructures , aims at publishing peer-reviewed research of original work in all areas of CARBON research including fullerenes, nanotubes, nanodiamond, graphene, any type of carbon nanostructure and any work dealing with carbon and carbon-related topics. Publishing high quality papers from all fields of carbon science and related topics, the journal intends to provide a means of communication between researchers who are interested in fundamental and applied carbon science issues.
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