Utilization of Activated Carbon/Magnesium(II) Composites in Decreasing Organic Materials

Dheasi Rani Ullica, Titin Anita Zaharah, Imelda Hotmarisi Silalahi
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Abstract

This study aimed to determine the characteristics, adsorption capacity, and isotherm of the adsorbent AC/Mg(II) composite in decreasing organic matter in peat water. Activated carbon was produced from empty fruit bunches of oil palm containing high levels of lignocellulose. Carbon was synthesized through the carbonization process and then activated with CH3COONa. The activated sample was composited with magnesium nitrate hexahydrate through an in-situ method under alkaline conditions using NaOH. The adsorbent AC/Mg(II) composite that had been prepared was characterized using FTIR, showing the presence of Mg-O bonds at the absorption wave number of 403.12 cm-1. The results showed that the moisture content of the adsorbent was lower compared to activated carbon, namely 1.30%. Furthermore, the best mass was 2 g AC/Mg(II) with an adsorption of 2.26 mg/g and an organic matter adsorption percentage of 14.41%. Furthermore, the optimum contact time was 15 minutes with an adsorption of 2.42 mg/g and a percentage of 17.15%. The mechanism occurring in the AC/Mg(II) composite with peat water organic matter followed the Langmuir isotherm equation, which formed a monolayer. The equation gave R2, adsorption capacity (Qo), and adsorption constant (k) values of 0.9994, 0.2340 mg/g, and 0.0047, respectively.

活性炭/镁(II)复合材料在减少有机材料中的应用
<div><table cellspacing="0" cellpadding="0" align="center"><tbody><tr><td align="left" valign="top">< >活性炭是由含有大量木质纤维素的油棕空果串制成的。通过炭化工艺合成碳,然后用CH<sub>3</sub>COONa活化。在碱性条件下,用氢氧化钠原位合成六水硝酸镁。用FTIR对所制备的吸附剂AC/Mg(II)复合材料进行了表征,在吸收波数为403.12 cm<sup>-1</sup>结果表明,该吸附剂的含水率较活性炭低,为1.30%。最佳质量为2 g AC/Mg(II),吸附量为2.26 Mg /g,有机物吸附率为14.41%。最佳吸附时间为15 min,吸附量为2.42 mg/g,吸附率为17.15%。AC/Mg(II)复合材料与泥炭水有机质的反应机理遵循Langmuir等温线方程,形成单层结构。由公式可得,R<sup>2</sup>吸附量(Qo)和吸附常数(k)分别为0.9994、0.2340 mg/g和0.0047。</p></td></tr></tbody></table></div>
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