Synthesis of Modified Walnut Shell Biochar and Its Performance of Cadmium Adsorption

Abstract

Biochar is a functional and environmentally friendly material mainly made from by-products of industrial and agricultural production as raw material, which is cracked at high temperatures and slow speeds. The preparation of biochar requires the thermochemical conversion of biomass in an oxygen-restricted environment. Different raw materials and preparation processes result in biochar with different internal structures and biofunctional groups, which often have different properties. Adsorption of heavy metal pollutants is one of the main research directions for biochar application, and there are still areas that can be improved in the current research for biochar for treating heavy metal wastewater. In this study, we take the treatment of cadmium-containing wastewater as an example, walnut shell biochar (WSBC) as a carrier, iron(VI) compounds as a modifying reagent, and test the performance of cadmium-containing wastewater treatment using simulated cadmium-containing wastewater by adjusting the pyrolysis process and modification method at the same time to find the optimal experimental scheme, and give a reasonable theoretical explanation in relation to the results of the characterization tests, such as SEM, FT-IR, and so on. The characterized results show that iron(VI) compound (K2FeO4)-modified WSBC has a significant ability to remove cadmium contamination in the wastewater (remove 96.62% of cadmium in 1 minute), and its structure is different from other iron compound-modified ones. The aim of this study is to improve the efficiency of cadmium adsorption by specific types of biochar, while realizing the whole process as environmentally friendly as possible.