Synergistic Effect of Polypyrrole-Polyaniline Conducting Polymer Nanocomposite and Fe3O4 Nanoparticles for Arsenite (III) Adsorption from wastewater

Haider Abbas, Muhammad Nadeem, Sumbal Tariq, Tahzeeb Zohra, Imran Ahmad, Tayyaba Munawar, Ashraf Hussain, Sidra Ahmad
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Abstract

For treatment of arsenic contaminated water, adsorption of arsenic and it’s reduction are there important processes. Conducting polymer efficiently show the efficient absorption but in use of it there is agglomeration of particles which make its usage difficult. To reduce this problem magnetic property material are used. In this polypyrrole and polyaniline conducting polymers were used. By oxidative polymerization of Polypyrrole and aniline in presence of Fe3O4 by utilizing FeCl3 nanocomposite was manufactured. In this magnetite prevented the agglomeration of particles of polymers and also helped in separation of nanocomposite from solution. Characterization was done by FTIR, SEM and XRD. This nanocomposite removal 88% arsenide (III) from aqueous solution at adsorbent concentration 0.01g and pH=1. Colorimetric method was used which developed complex with arsenite (III) and showed the removal of arsenite (III) from aqueous solution by complex. Separation of nanocomposite became easy due to magnetic properties of magnetite. This could be isolate from aqueous solution by using of strong magnet. This nanocomposite is the promising composite for removal of arsenite (III) from aqueous solution.
聚吡咯-聚苯胺导电聚合物纳米复合材料与Fe3O4纳米颗粒协同吸附废水中亚砷酸盐(III
砷的吸附和还原是处理砷污染水的重要过程。导电聚合物具有良好的吸附性能,但在使用过程中存在颗粒结块问题,给其使用带来困难。为了减少这一问题,采用了磁性材料。在此过程中使用了聚吡咯和聚苯胺导电聚合物。以FeCl3为原料,在Fe3O4存在下,将聚吡咯和苯胺进行氧化聚合制备纳米复合材料。在这种情况下,磁铁矿防止了聚合物颗粒的团聚,也有助于纳米复合材料从溶液中分离。采用FTIR、SEM、XRD等方法进行表征。该纳米复合材料在吸附剂浓度为0.01g、pH=1的条件下,可去除水中88%的砷化物(III)。用比色法与亚砷酸盐(III)形成配合物,表明配合物对水溶液中亚砷酸盐(III)的去除作用。由于磁铁矿的磁性,纳米复合材料的分离变得容易。利用强磁体可将其与水溶液分离。该纳米复合材料是一种很有前途的去除水溶液中亚砷酸盐(III)的复合材料。
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