PROSPECTS FOR THE EXTRACTION OF CHROMIUM FROM SLAG FERROCHROME PRODUCTION BY ACID METHOD

К.А. Kadirbekov, R.M. Chernyakova, R.A. Kaiynbayeva, G.Sh. Sultanbayeva, U.Zh. Jussipbekov, N.N. Kozhabekova
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Abstract

In the Republic of Kazakhstan, there is a noticeable upward trend in the volume of industrial waste, including from the production of ferrochrome. The problems of man-made pollution of the natural environment are becoming more acute every year, and are beginning to take on a global dimension. Technogenic ferrochrome production waste contains chromium, which is highly toxic and carcinogenic, which poisons water, soil, negatively affects the activity of all living organisms. Slags contain a significant number of valuable components used in various industries, and above all, chromium, which is irrevocably lost during storage. The main task still remains the development of industrial waste disposal processes that reduce the anthropogenic load on the biosphere and ensure the rational use of natural resources. The purpose of the work is to justify the choice of the method of processing the slags of the ferrochrome production. Conclusions: The analysis of the modern scientific and patent literature on acid processing and utilization of chromium-containing slags from the production of refined and high-carbon ferrochrome has been conducted. It should be noted that the described methods of various methods of processing ferrochrome production slags, despite their availability, are characterized by a multi-stage nature and do not allow complete processing of ferrochrome production slags in Kazakhstan. Currently, there is an excess of sulfuric acid production in Kazakhstan, so it becomes advisable to use sulfuric acid as a reagent for leaching chromium from slag from the production of ferrochromium. It can be expected that in sulfuric acid under certain conditions, such as heating, a sufficiently high degree of extraction of chromium (III) will be achieved in slags from the production of high-carbon chromium and in refined ferrochem slags.
酸法萃取铬铁渣中铬的研究前景
在哈萨克斯坦共和国,工业废料的数量有明显的上升趋势,包括生产铬铁产生的废料。人为污染自然环境的问题一年比一年严重,并开始具有全球性。技术改造铬铁生产废料含有铬,这是剧毒和致癌物,它毒害水,土壤,对所有生物的活动产生负面影响。炉渣含有大量用于各种工业的有价值的成分,其中最重要的是铬,它在储存过程中会不可挽回地丢失。主要任务仍然是发展工业废物处理工艺,减少对生物圈的人为负荷,确保合理利用自然资源。本研究的目的是为铬铁生产中炉渣处理方法的选择提供依据。结论:对精炼高碳铬铁生产中含铬渣酸处理利用的现代科学文献和专利文献进行了分析。应当指出的是,所描述的各种处理铬铁生产渣的方法,尽管它们是可用的,但其特点是多阶段的性质,并且不允许在哈萨克斯坦完全处理铬铁生产渣。目前,哈萨克斯坦硫酸生产过剩,采用硫酸作为浸出铬铁生产渣中铬的药剂是可取的。可以预期,在硫酸中,在某些条件下,如加热,将在高碳铬生产的渣和精炼的铁化渣中实现足够高程度的铬(III)的萃取。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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