A mixed Boltzmann–BGK model for inert gas mixtures

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Marzia Bisi, Maria Groppi, Enrico Lucchin, Giorgio Martalò
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引用次数: 0

Abstract

We propose a mixed Boltzmann–BGK model for mixtures of monatomic gases, where some kinds of collisions are described by bi–species Boltzmann operators and the others by the binary BGK terms given in [Bobylev et al., Kinetic and Related Models 11 (2018)], that is the relaxation model for mixtures with the closest structure to the Boltzmann one. At first, we assume that collisions occurring within the same species (intra-species) are modelled by Boltzmann operators, while interactions between different constituents (inter-species) are described by BGK terms. This option allows us to rigorously derive hydrodynamic equations not only in the classical collision dominated regime, but also in situations with intra–species collisions playing the dominant role (as in mixtures with very disparate particle masses). Then, we present a general form of this mixed Boltzmann–BGK model, characterized by further parameters allowing us to select which binary interactions have to be described by Boltzmann integrals or by BGK operators. We prove that this model preserves conservations of global momentum and energy, positivity of all temperatures and the validity of Boltzmann H-theorem, allowing us to conclude that the unique admissible equilibrium state is the expected Maxwellian distribution with all species sharing a common mean velocity and a common temperature.
惰性气体混合物的混合玻尔兹曼- bgk模型
我们提出了一个单原子气体混合物的混合玻尔兹曼- BGK模型,其中一些碰撞由双种玻尔兹曼算子描述,其他碰撞由[Bobylev等人,动力学和相关模型11(2018)]中给出的二元BGK项描述,这是结构最接近玻尔兹曼的混合物的松弛模型。首先,我们假设发生在同一物种内(物种内)的碰撞由玻尔兹曼算子建模,而不同成分之间(物种间)的相互作用由BGK项描述。这个选项允许我们严格推导流体动力学方程,不仅在经典的碰撞主导状态下,而且在种内碰撞起主导作用的情况下(如在粒子质量非常不同的混合物中)。然后,我们给出了这种混合Boltzmann - BGK模型的一般形式,其特征是进一步的参数允许我们选择哪些二元相互作用必须用Boltzmann积分或BGK算子来描述。我们证明了该模型保持了整体动量和能量守恒,所有温度的正性和玻尔兹曼h定理的有效性,从而使我们得出唯一可容许的平衡状态是所有物种共享共同平均速度和共同温度的期望麦克斯韦分布。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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