{"title":"Roles of different organic-inorganic hybrid interfaces in enhancing the mechanical properties of continuous basalt fiber/epoxy composites","authors":"Zhenhan Yan, Shengchang Zhang, Yingying Zhao, Qibin Xu, Mengjin Jiang, Pengqing Liu, Shiyi Zhou","doi":"10.1080/09276440.2023.2264041","DOIUrl":null,"url":null,"abstract":"ABSTRACTIn order to enhance the interfacial adhesion between continuous basalt fibers (CBFs) and epoxy (EP) matrix and the mechanical properties of resultant composites, the organic – inorganic hybrid compatibilization layer (OIHCL) composed of flexible 1,6-hexanediol diglycidyl ether (HDE) chains and rigid nano-silica (SiO2) is grafted on CBFs surface. With increasing the SiO2 content in the OIHCL, the structure and composition of the OIHCL change from a single layer composed of a well-dispersed SiO2 phase and continuous HDE phase to a double layer composed of an HDE/SiO2 inner-layer and aggregated SiO2 outer-layer. And, the effects of different OIHCLs on the mechanical performances of resultant composite are studied in details. The results show that the single-layer OIHCL exhibits stronger reinforcing effects in the interfacial shear strength (IFSS), tensile strength, and flexural strength of resultant composite. For example, the IFSS, tensile strength, and flexural strength of the CBFs-g-12.5%-(HDE/SiO2)/EP composite can reach 47.1 MPa, 466.1 MPa, and 660.5 MPa, respectively. Furthermore, the impact strength of the CBF/EP composites can be effectively enhanced by only grafting a flexible HDE layer on CBF surfaces. Finally, the aggregated SiO2 derived from the outer-layer of double-layer OIHCLs can deteriorate the interfacial adhesion, and all mechanical performances of resultant composites.KEYWORDS: Surface modificationinterface/interphasepolymer-matrix compositescontinuous basalt fibermechanical properties Disclosure statementThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.Author contributionsZ.Y. was mainly responsible for the most of experimental work and the related measurements. SC.Z. was mainly responsible for the experimental design, the result analysis, the manuscript writing, and the foundation supporting. Y.Z was responsible for the experiment work about Molecules Simulation. Q.X contributed to the analysis of the results. M.J was mainly responsible for the foundation supporting and the result analysis. P.L and SY.Z. were responsible for the experimental supervision and paper critical revision.Supplemental dataSupplemental data for this article can be accessed online at https://doi.org/10.1080/09276440.2023.2264041Additional informationFundingThe authors were grateful to the Science and Technology Program of Sichuan Province (No. 2023YFG0342) and the Open Project Program of Basalt Fiber and Composite Materials Key Laboratory of Sichuan Province (No. SZXX202004) for financial support.","PeriodicalId":10653,"journal":{"name":"Composite Interfaces","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composite Interfaces","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/09276440.2023.2264041","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
引用次数: 0
Abstract
ABSTRACTIn order to enhance the interfacial adhesion between continuous basalt fibers (CBFs) and epoxy (EP) matrix and the mechanical properties of resultant composites, the organic – inorganic hybrid compatibilization layer (OIHCL) composed of flexible 1,6-hexanediol diglycidyl ether (HDE) chains and rigid nano-silica (SiO2) is grafted on CBFs surface. With increasing the SiO2 content in the OIHCL, the structure and composition of the OIHCL change from a single layer composed of a well-dispersed SiO2 phase and continuous HDE phase to a double layer composed of an HDE/SiO2 inner-layer and aggregated SiO2 outer-layer. And, the effects of different OIHCLs on the mechanical performances of resultant composite are studied in details. The results show that the single-layer OIHCL exhibits stronger reinforcing effects in the interfacial shear strength (IFSS), tensile strength, and flexural strength of resultant composite. For example, the IFSS, tensile strength, and flexural strength of the CBFs-g-12.5%-(HDE/SiO2)/EP composite can reach 47.1 MPa, 466.1 MPa, and 660.5 MPa, respectively. Furthermore, the impact strength of the CBF/EP composites can be effectively enhanced by only grafting a flexible HDE layer on CBF surfaces. Finally, the aggregated SiO2 derived from the outer-layer of double-layer OIHCLs can deteriorate the interfacial adhesion, and all mechanical performances of resultant composites.KEYWORDS: Surface modificationinterface/interphasepolymer-matrix compositescontinuous basalt fibermechanical properties Disclosure statementThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.Author contributionsZ.Y. was mainly responsible for the most of experimental work and the related measurements. SC.Z. was mainly responsible for the experimental design, the result analysis, the manuscript writing, and the foundation supporting. Y.Z was responsible for the experiment work about Molecules Simulation. Q.X contributed to the analysis of the results. M.J was mainly responsible for the foundation supporting and the result analysis. P.L and SY.Z. were responsible for the experimental supervision and paper critical revision.Supplemental dataSupplemental data for this article can be accessed online at https://doi.org/10.1080/09276440.2023.2264041Additional informationFundingThe authors were grateful to the Science and Technology Program of Sichuan Province (No. 2023YFG0342) and the Open Project Program of Basalt Fiber and Composite Materials Key Laboratory of Sichuan Province (No. SZXX202004) for financial support.
期刊介绍:
Composite Interfaces publishes interdisciplinary scientific and engineering research articles on composite interfaces/interphases and their related phenomena. Presenting new concepts for the fundamental understanding of composite interface study, the journal balances interest in chemistry, physical properties, mechanical properties, molecular structures, characterization techniques and theories.
Composite Interfaces covers a wide range of topics including - but not restricted to:
-surface treatment of reinforcing fibers and fillers-
effect of interface structure on mechanical properties, physical properties, curing and rheology-
coupling agents-
synthesis of matrices designed to promote adhesion-
molecular and atomic characterization of interfaces-
interfacial morphology-
dynamic mechanical study of interphases-
interfacial compatibilization-
adsorption-
tribology-
composites with organic, inorganic and metallic materials-
composites applied to aerospace, automotive, appliances, electronics, construction, marine, optical and biomedical fields