INVESTIGATION OF ARYLALKYLATION REACTIONS OF LIQUID PRODUCTS OF PYROLYSIS WITH 130-190°C FRACTION IN THE PRESENCE OF HYDROCHLORIC ACID IMPREGNATED KH-30 CATALYST OF PHENOL

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Abstract

Alkylation reactions of 130-190°C fraction of liquid products of pyrolysis with the presence of KH-30 catalyst impregnated with hydrochloric acid of phenol were studied. As a result, the effect of various parameters - reaction temperature, duration, molar ratios of initial components and the amount of catalyst - on the yield and selectivity of the target product was investigated. It was determined that the yield of para-arylalkylphenol is 78.6%, and the selectivity is 94.3%. Although more than 100 years have passed since the study of alkylation reactions of phenol, the preparation of alkylphenols and their various derivatives has not lost its relevance even today. Alkylphenol-based chemical compounds are finding new effective areas of use: they are insecticides, pesticides, etc. against agricultural pests. they are used as a ligand for catalytic precursors used in the production, oligo- and polymerization of olefins, and as an extractant in the purification of oil fractions from aromatic hydrocarbons. Keywords: phenol, fraction 130-190°C, catalyst, arylalkylation, para-arylalkylphenol.
130 ~ 190℃馏分热解液体产物在盐酸浸渍kh-30苯酚催化剂作用下芳基烷基化反应的研究
研究了苯酚盐酸浸渍KH-30催化剂在130 ~ 190℃热解液产物中的烷基化反应。研究了反应温度、反应时间、初始组分摩尔比和催化剂用量等参数对目标产物收率和选择性的影响。结果表明,对芳基烷基酚的收率为78.6%,选择性为94.3%。虽然苯酚的烷基化反应的研究已经过去了100多年,但烷基酚及其各种衍生物的制备直到今天也没有失去其相关性。烷基酚类化合物正在寻找新的有效使用领域:它们是杀虫剂、除害剂等对付农业害虫。它们在烯烃的生产、低聚和聚合中用作催化前体的配体,在芳香烃的油馏分提纯中用作萃取剂。关键词:苯酚,馏分130-190℃,催化剂,芳基烷基化,对芳基烷基酚。
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