Mechanisms of formation of wear-resistant dissipative structures in non-stationary lubrication conditions

O. A. Ilina, O. O. Mikosianchyk, R.H. Mnatsakanov, R.E. Kostyunik, O.P. Yashchuk, M.A. Shteinyk
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Abstract

The work aimed to determine the influence of the processes of supramolecular self-organization in the lubricating layer on the patterns of wear of friction pairs. The mechanisms of structural adaptability of tribocoupler elements were analyzed, and the regularities of the manifestation of a large-scale and energy jump, which characterizes the transition of the tribosystem to a metastable state, were determined. An evaluation of the tribotechnical characteristics of commercial transmission oils was carried out on a software-hardware complex that, using a roller analogy, simulates the operation of gears in conditions of rolling with slipping. It was established that the activation of contact surfaces in the mode of frequent starts and stops leads to active interaction of the lubricant's components and the metal's surface layers with the gradual formation of boundary adsorption layers. For transmission oil 'Bora B' T-Shyp, an increase in anti-friction properties has been established due to the effective lubricating ability of the oil when forming the hydro- and non-hydrodynamic components of the lubricating layer thickness. The effect of the chemical activity of the zinc dialkyl dithiophosphate antiwear additive and the hydrocarbon components of the base of transmission oils on the effectiveness of the formation of boundary films is considered. It was determined that the formation of stable boundary films of the lubricant is the leading process in manifesting their damping properties concerning the localization of elastic-plastic deformation along the depth of the metal. When boundary films are formed on 90-95% of the contact area, the change in the microstructure of the near-surface layers is fixed at a depth of up to 20 microns; when boundary films are formed on 20...50% of the surface area, the spread of elastic-plastic deformation reaches a depth of up to 50 microns. The kinetics of the formation of boundary films by the lubricant and the indicators of the specific work of friction in contact are correlated with the intensity of wear of the contact surfaces
非稳态润滑条件下耐磨耗散结构的形成机制
本工作旨在确定润滑层超分子自组织过程对摩擦副磨损模式的影响。分析了摩擦耦合器元件的结构适应性机理,确定了摩擦系统向亚稳态过渡时出现大尺度和能量跳变的规律。对商用变速箱油的摩擦技术特性进行了评估,在软件-硬件复合体上,使用滚子类比,模拟齿轮在滑动滚动条件下的操作。研究发现,频繁启停模式下接触面的活化导致润滑油各组分与金属表层的主动相互作用,并逐渐形成边界吸附层。对于变速箱油“Bora B”T-Shyp,由于在形成润滑层厚度的水力和非水力成分时,油的有效润滑能力,已经建立了抗摩擦性能的增加。考虑了二烷基二硫代磷酸锌抗磨添加剂的化学活性和传动油基体的碳氢化合物组分对边界膜形成效果的影响。结果表明,润滑油沿深度的弹塑性局部化过程中,稳定边界膜的形成是体现其阻尼特性的主要过程。当在接触面积的90-95%处形成边界膜时,近表层微观结构的变化在深度达20微米处是固定的;当边界膜在20…在表面积的50%处,弹塑性变形的扩散深度可达50微米。润滑油形成边界膜的动力学和接触摩擦比功指标与接触面磨损强度有关
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