Penentuan Kondisi Optimum Desorpsi Anion Nitrat (NO3-) pada Silika Mesopori Termodifikasi Dimetilamina (DMA)

Dipnorita Retno, Budhi Oktavia, Indang Dewata, Miftahul Khair
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Abstract

Mesoporous silica is an inorganic materials that has high potential to be applied in various industrial fields, one of its application is the adsorption method. To maximize the adsorption of mesoporous silica, modification of the silica surface was carried out with the addition of amine compounds. The amine compound used as a modifier is dimethylamine (DMA). Mesoporous silica which has been modified with dimethylamine is used in the nitrate anions adsorption process by the column method. The adsorption capacity of the nitrate anion is 0.0917 mg/g. After being adsorbed, the desorption process was carried out to release the adsorbed nitrate anions again. From the desorption process, it was found that HCl proved to be the best desorption agent used on nitrate anions. The optimum concentration of HCl was 0.15 M with the number of nitrate anions desorbed as much as 0.0459 mg with a 100% desorption percentage.
确定经内硅胶和二甲胺(DMA)的硝酸苯胺消化道(NO3-)的最佳降解条件
介孔二氧化硅是一种具有很高应用潜力的无机材料,其应用之一是吸附法。为了最大限度地提高介孔二氧化硅的吸附性能,对二氧化硅表面进行了胺类化合物的改性。用作改性剂的胺类化合物是二甲胺(DMA)。采用二甲胺改性的介孔二氧化硅用于柱法吸附硝酸盐阴离子。对硝酸盐阴离子的吸附量为0.0917 mg/g。吸附后进行解吸,将吸附后的硝酸盐阴离子再次释放。从解吸过程中发现,HCl是硝酸根阴离子的最佳解吸剂。HCl的最佳浓度为0.15 M,硝酸根负离子的解吸量可达0.0459 mg,解吸率为100%。
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