Synthesis of Graphene Oxide using Hummers Method as Adsorbent of Malachite Green Dye

Amri Amri, Yulizah Hanifah
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Abstract

Graphene oxide materials were successfully synthesized using the Hummer method with XRD, FTIR, and BET characterization results. Graphene oxide material was used as malachite green dye adsorbent. The surface area of graphene oxide material and the maximum adsorption capacity were 157.360 m2/g and 106.383 mg/g. The selectivity process of graphene oxide material to the three dyes showed the most effective malachite green dye. The optimum pH of adsorption was obtained at pH 4. The optimum time of adsorption occurred at 120 minutes and the kinetics model followed PSO. The isotherm data followed Langmuir isotherm and the adsorption process was endoetrmic and spontaneous. The regeneration results showed the ability up to five cycles with a decrease of 40.019% from 96.698% to 56.679%.
用Hummers法合成孔雀石绿染料吸附剂氧化石墨烯
采用Hummer法成功合成了氧化石墨烯材料,并对其进行了XRD、FTIR和BET表征。采用氧化石墨烯材料作为孔雀石绿染料吸附剂。氧化石墨烯材料的表面积和最大吸附容量分别为157.360 m2/g和106.383 mg/g。氧化石墨烯材料对三种染料的选择性过程表明,孔雀石绿染料的选择性效果最好。最佳吸附pH值为pH 4。最佳吸附时间为120 min,动力学模型符合PSO。等温线数据符合Langmuir等温线,吸附过程为内源性自发吸附。再生率从96.698%下降到56.679%,下降了40.019%。
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