Hendradi Hardhienata, Hasan Al Kharfan, Salim Faci, Muhammad Birowosuto, Husin Alatas
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引用次数: 0
Abstract
We apply the simplified-bond-hyperpolarizability model (SBHM) to investigate second harmonic generation (SHG) from tetragonal and orthorhombic methylammonium (MA) lead (Pb) iodide (I) perovskite structures. Assuming that the SHG radiation comes from the anharmonic charges parallel to the Pb-I covalent bond vectors, we show explicitly how the reflective rotational anysotropy SHG (RASHG) intensity profiles arise via dipole superposition from the perovskite surface and that their bulk contribution is zero for both the tetragonal and orthorhombic bulk structures if the contribution from MA molecules can be neglected. In addition, we compare the third order susceptibility tensor obtained from group theory and SBHM and calculate the values for the nonzero components as well as derive the SHG intensity field formulas. We found that the tetragonal and orthorhombic perovskite SHG intensity profiles are different. Furthermore, our results show that even in relative complex systems such as metal halide perovskites (MHPs), RASHG experimental data can be fitted using only one independent fitting parameter, which is the effective Pb-I nonlinear hyperpolarizability. Therefore, the analysis of perovskite using an anharmonic bond model can lead to better efficiencies of photovoltaic devices, while it will also pave a way for the use of SHG in MHP crystals as frequency conversion and optical signal processing.
期刊介绍:
The Journal of the Optical Society of America B (JOSA B) is a general optics research journal that complements JOSA A. It emphasizes scientific research on the fundamentals of the interaction of light with matter such as quantum optics, nonlinear optics, and laser physics. Topics include:
Advanced Instrumentation and Measurements
Fiber Optics and Fiber Lasers
Lasers and Other Light Sources from THz to XUV
Light-Induced Phenomena
Nonlinear and High Field Optics
Optical Materials
Optics Modes and Structured Light
Optomechanics
Metamaterials
Nanomaterials
Photonics and Semiconductor Optics
Physical Optics
Plasmonics
Quantum Optics and Entanglement
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Surface Optics
Ultrafast Optical Phenomena
Wave Guiding and Optical Confinement
JOSA B considers original research articles, feature issue contributions, invited reviews and tutorials, and comments on published articles.