Study on Single Chip Integrated Methane Sensor based on MEMS Process

Kai Zhang, Hongquan Zhang, Ben Mao, Mikolai Mukhurov
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Abstract

For decades, globular black-white catalytic gas sensor has the problems of handmade, large element dispersion and matching difficulty. To solve these problems, with combination of silicon-based MEMS technology and nanometer technology, an idea of integrating sensitive components of catalytic sensors and compensation components together into a chip is proposed. $\gamma$-Al2O3/ZrO2 active carriers are created using chemical co-precipitation method and stabilization modification with ThO2+CeO2using doping technology (Pd and Pt as catalysts). In order to fabricate catalytic gas sensors with integration, sensor chip and heat sensitive electrode are manufactured by silicon MEMS and high pure platinum film production process so that the catalytic sensitive elements and temperature-humidity compensating element can be integrated on micro bridge. The results show that the sensor has a fast response to methane gas, with 90% response time of 10s and recovery time of 12s. The average sensitivity of the sensor output is 15mv/1%CH4.
基于MEMS工艺的单片机集成甲烷传感器研究
几十年来,球形黑白催化气体传感器存在手工制作、元件分散大、匹配困难等问题。为了解决这些问题,结合硅基MEMS技术和纳米技术,提出了将催化传感器的敏感元件和补偿元件集成到一个芯片上的想法。采用化学共沉淀法制备了$\gamma$-Al2O3/ZrO2活性载体,并采用掺杂技术对ThO2+ ceo_2进行了稳定化改性(Pd和Pt为催化剂)。为了制造集成化的催化气体传感器,采用硅MEMS和高纯铂膜生产工艺制造传感器芯片和热敏电极,将催化敏感元件和温湿度补偿元件集成在微桥上。结果表明,该传感器对甲烷气体的响应速度快,90%的响应时间为10s,恢复时间为12s。传感器输出的平均灵敏度为15mv/1%CH4。
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