Lead-Free Hybrid Perovskite Light-Harvesting Material for QD-LED Application

R. Singh, N. Jain, S. Som, S. Dutta, Jai Singh, Ranveer Kumar
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Abstract

Most recently, organic-inorganic semiconductor light harvester materials, have arisen as a new class of functional element and attracts the research community due to its outstanding optoelectronic properties. Organic-inorganic perovskites are solution process that is easy for the fabrication of devices at low temperature. Additionally, up to date, perovskite quantum dots have emerged as the most efficient light harvester for LEDs and display applications, with high color purity, color tunability, and photoluminescence quantum yield up to 100%. However, the presence of lead in organic-inorganic perovskites and the stability issue of perovskite materials are the significant challenges for the research community. To date, some lead substitute materials have been tried to enhance the film morphology and production of the less toxic light harvester. In this chapter, we focus on the lead substitution on B sight with homovalent cations like Sn 2+ , Mn 2+ , Cd 2+ , and Zn 2+ cations. These lead substitutions not only reduce the toxicity of perovskite material while these dopants also enhance the optical and performance of LEDs. We also included the LEDs application of lead substituted perovskite quantum dots (PQDs) that may be useful for the environmental friendly and highly performing perovskite quantum dot LEDs (PQ-LEDs) shortly.
应用于QD-LED的无铅杂化钙钛矿捕光材料
近年来,有机-无机半导体光收获材料作为一类新型的功能元件,因其优异的光电性能而备受研究界的关注。有机-无机钙钛矿是一种易于在低温下制备器件的固溶工艺。此外,到目前为止,钙钛矿量子点已成为led和显示应用中最有效的光收集器,具有高颜色纯度,颜色可调性和高达100%的光致发光量子产率。然而,铅在有机-无机钙钛矿中的存在以及钙钛矿材料的稳定性问题是研究界面临的重大挑战。迄今为止,已经尝试了一些铅替代材料来改善薄膜形态和生产毒性较小的光收集器。在本章中,我们重点研究了铅在B视线上与同价阳离子如Sn 2+、Mn 2+、Cd 2+和zn2 +阳离子的取代。这些铅替代品不仅降低了钙钛矿材料的毒性,而且这些掺杂剂还增强了led的光学和性能。我们还介绍了铅取代钙钛矿量子点(PQDs)在led中的应用,这可能对环境友好和高性能的钙钛矿量子点led (pq - led)有帮助。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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