REAPROVEITAMENTO DA TORTA DE MORINGA OLEÍFERA LAM. PARA TRATAMENTO DE MATRIZ MULTIELEMENTAR

Wallas Douglas de Macêdo Souza
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Abstract

Introduction: Faced with the problem of environmental pollution, with emphasis on the availability and maintenance of good quality of water resources, as well as the correct allocation of solid waste, there is a demand for low-cost and versatile technologies for wastewater treatment. Biosorption using agro-industrial residues has been investigated as a possibility to address this issue, due to the ability of the functional groups of biosorbents to allow bonds and formation of complexes with metals. Objetive: In this work, the objective was to investigate the potential of the cake from the extraction of biodiesel from the oilseed Moringa Oleífera Lam. in the removal of heavy metals from multielement matrices. Methodology: For this, the seeds of the species were collected, submitted to the production of biodiesel and, then, the cake was applied in biosorption tests, conducted under agitation, using 1 g of biosorbent, for 1 h in a matrix composed of 1 ppm of each one of the metals (Cd, Cr, Cu, Ni, Pb and Zn). The capture of metals was monitored by Atomic Absorption Spectroscopy and the plant matrix was also characterized by the X-Ray Fluorescence technique, regarding the possible natural occurrence of the respective metals. Results: Metal removal ranged from 25% to 80%, with emphasis on Cu and Pb, in which 80% was captured for both. It was also identified the presence of Cu and Zn in the biomass, possibly absorbed through the soil. Conclusion: Considering that industrial effluents have a wide range of metals, it is believed that other chemical components and parameters inherent to biosorption can interfere in the process. Therefore, more conditions need to be evaluated to maximize the scale and make the use of biosorbents viable.
辣木派oleifera LAM的再利用。用于多元素矩阵处理
导论:面对环境污染问题,强调水资源的可用性和保持良好的质量,以及固体废物的正确分配,需要低成本和通用的废水处理技术。由于生物吸附剂的官能团允许与金属结合并形成配合物的能力,利用农业工业残留物进行生物吸附已被研究作为解决这一问题的可能性。目的:探讨从油籽辣木Oleífera Lam中提取生物柴油的饼的潜力。从多元素基质中去除重金属。方法:为此,收集该物种的种子,将其提交到生物柴油的生产中,然后将饼用于生物吸附试验,在搅拌下进行,使用1 g生物吸附剂,在由1 ppm的每种金属(Cd, Cr, Cu, Ni, Pb和Zn)组成的基质中进行1小时。利用原子吸收光谱法监测金属的捕获,并利用x射线荧光技术对植物基质进行表征,以确定各自金属可能的自然存在。结果:金属去除率在25% ~ 80%之间,以Cu和Pb为重点,两者的去除率均为80%。生物量中还存在Cu和Zn,可能是通过土壤吸收的。结论:考虑到工业废水中金属的种类广泛,认为生物吸附过程中存在其他化学成分和固有参数的干扰。因此,需要评估更多的条件,以最大限度地扩大规模,使生物吸附剂的使用可行。
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