Synthesis and luminescence properties of calcium phosphates

A. Terebilenko, K. Terebilenko, N. Slobodyanik, E. Zubar’
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Abstract

The main crystallization trends of complex oxide compounds of yttrium and calcium from potassium phosphate-molybdate melts have been studied. The regions of formation K3Y(PO4)2, YPO4, KCaY(PO4)2 and K2CaP2O7 from high-temperature solutions of K-Ca-Y-P-Mo-O have been distinguished. The influence of K/Mo and P/Ca ratio in the initial melt has been shown to play the key role in solid phase formation.
磷酸钙的合成及其发光性能
研究了磷酸钾钼酸盐熔体中钇、钙复合氧化物的主要结晶趋势。区分了K-Ca-Y-P-Mo-O高温溶液中K3Y(PO4)2、YPO4、KCaY(PO4)2和K2CaP2O7的生成区域。初始熔体中K/Mo和P/Ca比值的影响在固相形成中起关键作用。
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