Study of Lowest Odd Parity Configurations in Ge-I Like Ions

A. Wajid, S. Jabeen
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Abstract

Fine structure energy levels, transition probabilities and oscillator strength for terms belonging to the ground configuration, \(\rm 4s^{2}4p^{2}\) and the first exited odd parity configurations \(\rm 4s4p^{3}\), \(\rm 4s^24p5s\) and \(\rm 4s^{2}4p4d\) of Ge-I like ions have been calculated using Hartree-Fock method with relativistic correction incorporating large number of interacting configurations \(\rm[4s^{2}4p(4f+5p+5g), 4s4p^{2}(4d+5s), 4p^{3}(4d+5s)]\). Experimentally reported levels have been compared with theoretical results establishing energy parameters in the first eleven members of the sequence (Ge I-Mo XI). The configuration \(\rm 4s^{2}4p4d\) in Rb VI, Sr VII, and \(\rm 4s4p^3\) except \(\rm 4s4p^{3}\) \(\rm^{5}S_2\) level in Ge-I, are not observed yet. A systematic study of Slater parameters in the isoelectronic sequence enabled us to make precise predictions of the missing energy levels belonging to these configurations.
类锗离子中最低奇宇称组态的研究
精细结构能级、跃迁概率和属于地面构型的振子强度; \(\rm 4s^{2}4p^{2}\) 第一个是奇数奇偶校验配置 \(\rm 4s4p^{3}\), \(\rm 4s^24p5s\) 和 \(\rm 4s^{2}4p4d\) 采用Hartree-Fock方法,结合大量相互作用组态进行相对论修正,计算了类锗离子(Ge-I)的量子密度 \(\rm[4s^{2}4p(4f+5p+5g), 4s4p^{2}(4d+5s), 4p^{3}(4d+5s)]\). \(\rm 4s^{2}4p4d\) 在Rb VI, Sr VII,和 \(\rm 4s4p^3\) 除了 \(\rm 4s4p^{3}\) \(\rm^{5}S_2\) 在Ge-I的水平,还没有观察到。对等电子序列中斯莱特参数的系统研究使我们能够对属于这些构型的缺失能级作出精确的预测。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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