Using a Novel Heterojunction CoWO4/g-C3N4 as Visible Light Photocatalyst for Photodegradation of Organic Pollutant

Do Van Dang, Tran Thi Chi Linh, L. T. Sơn
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Abstract

Methylene Blue (MB) is a common dye that has various applications in different fields, including medicine, biology, and environmental science. While it can be beneficial in certain contexts, it can also have negative effects on the environment under certain circumstances. In this study, the photodegradation of MB under visible light irradiation using a novel heterojunction CoWO4/g-C3N4 catalyst was investigated. A series of CoWO4/g-C3N4 composites were synthesized and characterized using various techniques, including XRD, SEM, SEM-EDS, FT-IR, and UV–DRS. The results revealed that the 0.3CoWO4/g-C3N4 composite showed the highest efficiency (93%) in degrading MB during the 80-minute photodegradation process, aligning with the pseudo-first-order kinetics. The results provide clear evidence that the formation of CoWO4/g-C3N4 heterojunction greatly enhances the efficiency of photocatalysis by facilitating the swift separation of electron-hole pairs and boosting the redox capability. Additionally, the photodegradation efficiency remained above 90% even after four cycles, suggesting the stability of the catalyst.  
新型异质结CoWO4/g-C3N4作为可见光催化剂光降解有机污染物
亚甲基蓝(MB)是一种常见的染料,在医学、生物学和环境科学等不同领域都有广泛的应用。虽然在某些情况下它可能是有益的,但在某些情况下它也可能对环境产生负面影响。在本研究中,采用新型异质结CoWO4/g-C3N4催化剂,研究了可见光下MB的光降解。合成了一系列CoWO4/g-C3N4复合材料,并采用XRD、SEM、SEM- eds、FT-IR、UV-DRS等技术对其进行了表征。结果表明,在80分钟的光降解过程中,0.3CoWO4/g-C3N4复合材料对MB的降解效率最高(93%),符合准一级动力学。结果表明,CoWO4/g-C3N4异质结的形成通过促进电子-空穴对的快速分离和提高氧化还原能力,大大提高了光催化效率。此外,经过4次循环后,光降解效率仍保持在90%以上,表明催化剂的稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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