Preliminary evaluation of the decontaminating potential of a manganese oxide supported on mordenite

G. Vázquez-Rodríguez, Perla Rubí Trejo-Bustillos
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Abstract

The treatment and in situ reuse of greywater could greatly contribute to reduce the water demand at the municipal level, thereby achieving social, economic, and environmental benefits. Decentralized treatment systems use chemical, physical and biological methods to decontaminate water, which then allows its reuse in garden irrigation, filling toilets or cleaning without primary contact with the inhabitants of the home, among other uses. In several of these systems (such as submerged wetlands or biofilters), filter materials are used. For example, zeolites and manganese oxides (MnOx) are reported in the literature as excellent candidates for use in water treatment due to their adsorption properties and, in the case of the latter, to its oxidation potential. In this work, a coating with a manganese oxide was carried out through a precipitation reaction on mordenite-type zeolitic material, to be used as a filter material in decentralized greywater treatment systems. The synthetized composite material was analyzed by the methylene blue adsorption test and the experimental data was adjusted to the Langmuir Isotherm model. The value of the specific surface area of the MnOx-coated mordenite-type zeolite was also estimated. With this analysis, it was possible to obtain preliminary results about the capacity of this material to decontaminate household greywater, which needs to be confirmed by further research.
丝光沸石负载氧化锰去污潜能的初步评价
灰水的处理和就地回用可以大大有助于减少城市一级的用水需求,从而实现社会、经济和环境效益。分散式处理系统使用化学、物理和生物方法对水进行净化,然后将其重新用于花园灌溉、填充厕所或清洁,而无需与家庭居民进行主要接触,以及其他用途。在一些这样的系统(如淹没湿地或生物过滤器)中,使用过滤材料。例如,沸石和锰氧化物(MnOx)在文献中被报道为水处理中使用的优秀候选者,因为它们的吸附特性,在后者的情况下,由于其氧化电位。在这项工作中,通过沉淀反应在丝光沸石型沸石材料上进行了氧化锰涂层,作为分散灰水处理系统的过滤材料。对合成的复合材料进行了亚甲基蓝吸附实验,并将实验数据调整为Langmuir等温线模型。并对mnox包覆的丝光沸石型沸石的比表面积进行了估算。通过这一分析,有可能获得关于这种材料净化家庭灰水的能力的初步结果,这需要通过进一步的研究来证实。
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