Effect of AlSb quantum dots on efficiency of GaAs solar cell (Conference Presentation)

A. Mansoori, S. Addamane, E. Renteria, D. Shima, C. Hains, G. Balakrishnan
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Abstract

Quantum Dots (QDs) have a broad applications in science and specifically in solar cell. Many research groups show that by adding QDs with lower bandgap respect to host material, the overall absorption of sun spectrum coverage will increase. Here, we propose using QDs with higher band gap respect to host material to improve efficiency of solar cell by improving quantum efficiency. GaAs solar cells have the highest efficiency in single junction solar cells. However, the absorption of GaAs is not good enough in wavelength lower than 550nm. AlSb can absorb shorter wavelength with higher absorption coefficient and also recombination rate should be lower because of higher bandgap of AlSb respect to GaAs. We embed AlSb QDs in GaAs solar cells and results show slight improvement in quantum efficiency and also in overall efficiency. Coverage of AlSb QDs has a direct impact on quality of AlSb QDs and efficiency of cell. In the higher coverage, intermixing between GaAs and AlSb causes to shift bandgap to lower value (having AlGaSb QDs instead of pure AlSb QDs). This intermixing decrease the Voc and overall efficiency of cell. In lower coverage, AlSb can survive from intermixing and overall performance of cell improves. Optimizing growth condition of AlSb QDs is a key point for this work. By using AlSb QDs, we can decrease the thickness of active layer of GaAs solar cells and have a thinner solar cell.
AlSb量子点对砷化镓太阳能电池效率的影响(会议报告)
量子点在科学上有着广泛的应用,特别是在太阳能电池中。许多研究小组表明,通过添加相对于宿主材料具有更低带隙的量子点,太阳光谱覆盖的总体吸收将增加。在这里,我们提出使用相对于宿主材料具有更高带隙的量子点,通过提高量子效率来提高太阳能电池的效率。砷化镓太阳能电池是单结太阳能电池中效率最高的。然而,在低于550nm的波长,对GaAs的吸收不够好。AlSb相对于砷化镓的带隙较大,吸收系数较高,吸收波长较短,复合率也较低。我们在砷化镓太阳能电池中嵌入了AlSb量子点,结果表明量子效率和总效率都有轻微的提高。AlSb量子点的覆盖范围直接影响到AlSb量子点的质量和细胞效率。在较高的覆盖范围内,GaAs和AlSb之间的混合导致带隙向较低的值移动(具有AlGaSb量子点而不是纯AlSb量子点)。这种混合降低了挥发性有机化合物和电池的整体效率。在低覆盖条件下,AlSb可以在混合中存活,提高了电池的整体性能。优化AlSb量子点的生长条件是本研究的重点。利用AlSb量子点可以减小砷化镓太阳电池的有源层厚度,使太阳电池更薄。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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