Kinetics of reanodization of porous anodic oxide films on aluminium formed in pore-forming solutions of various acids

A. Zahariev, B. Tzaneva, C. Girginov, S. Andreev
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Abstract

Investigations are carried out towards reanodization of porous anodic oxide films on aluminium formed in aqueous solutions of sulphuric, oxalic and chromic acid. These films are prepared in a way to have one and the same porosity. It is found out that in case of equal porosity the slopes of the kinetic voltage-time curves recorded during reanodization are different. The effect of the anionic species incorporated from electrolyte solution into the porous template could be a probable explanation for the dissimilar rates of barrier layer growth.
在不同酸的成孔溶液中形成的铝表面多孔阳极氧化膜的再阳极化动力学
研究了在硫酸、草酸和铬酸水溶液中形成的多孔铝阳极氧化膜的再氧化过程。这些薄膜的制备方法是使其具有相同的孔隙度。结果表明,在孔隙率相等的情况下,再氧化过程中记录的动态电压-时间曲线斜率不同。从电解质溶液中加入到多孔模板中的阴离子可能是阻挡层生长速率不同的一个可能的解释。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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