Water Hyacinth Derived Mixed-Oxide Heterogeneous Catalyst for Biodiesel Production

Minakshi Gohain, D. Deka
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引用次数: 4

Abstract

Homogeneous catalytic system for biodiesel synthesis is no longer justifiable by industries in the near future; mainly due to ecological issues related to the conventional homogeneous catalytic system like problems associated with separation of the catalyst from the product, reusability, and its release into the environment after washing the catalyst from the product. The present study is focused on the viability of environmentally benign heterogeneous catalyst synthesis from water hyacinth (WH) a renewable aquatic plant considered hazard for other useful aquatic crops. The synthesized catalyst was characterized by fourier transform infrared spectroscopy (FTIR), powder X-ray diffractograms (XRD), energy dispersive analysis of X-ray (EDAX), brunauer-emmett-teller (BET), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and hammett indicator analysis. The catalyst demonstrated a superior catalytic performance achieving fatty acid methyl esters (FAME) conversion of 97.1 % in 3 h. The catalyst could be reused efficiently with FAME conversion of more than 80 % after the third cycles. The present work reveals the possibility of developing heterogeneous catalyst from an aquatic weed for FAME synthesis, reducing the total production cost of biodiesel synthesis.
水葫芦衍生的混合氧化物多相催化剂用于生物柴油生产
均相催化系统合成生物柴油在不久的将来不再是合理的工业;主要是由于与传统的均相催化系统相关的生态问题,如催化剂与产品的分离、可重用性以及催化剂从产品中洗涤后释放到环境中的问题。水葫芦是一种可再生的水生植物,被认为对其他有用的水生作物有危害,本研究的重点是利用水葫芦合成环境友好的多相催化剂的可行性。采用傅里叶红外光谱(FTIR)、粉末x射线衍射(XRD)、x射线能量色散分析(EDAX)、brunauer-emmett-teller (BET)、扫描电镜(SEM)、透射电镜(TEM)和hammett指示剂分析对合成的催化剂进行了表征。该催化剂具有良好的催化性能,3 h内脂肪酸甲酯(FAME)的转化率为97.1%,第三次循环后,FAME的转化率可达80%以上,可有效重复使用。本研究揭示了从水草中开发合成FAME的多相催化剂的可能性,从而降低了生物柴油合成的总生产成本。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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