[Study on visible-light curing soft resins consisting of fluoropolymers. 1. Effect of fluoroalkyl methacrylate monomers].

Y Ohe, Y Kadoma, Y Imai
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Abstract

New experimental visible-light cured soft resins were prepared by combining 4 kinds of fluoroalkyl methacrylate monomers with a vinylidene fluoride/hexafluoropropylene copolymer, or a vinylidene fluoride/tettrafluroethylene/hexafluoropropylene copolymer. Some properties of the resins prepared were examined to determine their value as a soft denture liner material. Water contact angles were more than 90 degrees in all cases and increased with the increase in the number of fluorine atoms in the fluoroalkyl groups. Hardness (JIS A) was less than 50 for the softes resin. Water sorption after 10 weeks was 3-4.5 wt %. Solubility 0.1-0.3 wt% and amount of residual monomer 0.2 wt% were very low. The properties of these new experimental resins were comparable or superior to the commercial soft materials available.

含氟聚合物软树脂的可见光固化研究。1. 甲基丙烯酸氟烷基单体的影响[j]。
将4种甲基丙烯酸氟烷基单体与偏氟乙烯/六氟丙烯共聚物、偏氟乙烯/四氟乙烯/六氟丙烯共聚物复配,制备了新型可见光固化软树脂。对所制备树脂的一些性能进行了测试,以确定其作为软性义齿衬垫材料的价值。在所有情况下,水的接触角都大于90度,并且随着氟烷基中氟原子数目的增加而增加。软树脂的硬度(JIS A)小于50。10周后吸水率为3-4.5 wt %。溶解度0.1 ~ 0.3 wt%,单体残留量0.2 wt%都很低。这些新的实验树脂的性能与现有的商用软材料相当或更好。
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