Enhancement of Intensity of Emission and Photoluminescence Properties of Red Light Emitting YPO4:Eu3+ by Infiltration of Li+ in the Crystal Structure of YPO4:Eu3+

D. Pyngrope, A. Prasad, R. Pradhan
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Abstract

Red light emitting YPO4: Eu3+ and YPO4: Tb3+: Li+ nanoparticles were synthesised using polyol method at low temperatures. The phase purity, micromorphology, and luminescence characteristics were studied using Transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier Transfer Infrared absorption spectroscopy (FT-IR). Combined XRD and TEM analysis showed that the YPO4 nanoparticles crystallized into a single phase of tetragonal (I41/amd) structure. The energy transfer from Li+ ions to Eu3+ ions was tested by studying the photoluminescence properties of YPO4: Eu3+and YPO4: Eu3+: Li+ nanoparticles and how it results in the improvement of the luminescence intensity.
Li+在YPO4:Eu3+晶体结构中渗透增强YPO4:Eu3+红光发射强度和光致发光性能
采用多元醇法制备了YPO4: Eu3+和YPO4: Tb3+: Li+红色发光纳米粒子。采用透射电子显微镜(TEM)、x射线衍射仪(XRD)和傅里叶转移红外吸收光谱(FT-IR)研究了相纯度、微观形貌和发光特性。XRD和TEM结合分析表明,YPO4纳米颗粒结晶为单相四方(I41/amd)结构。通过研究YPO4: Eu3+和YPO4: Eu3+: Li+纳米粒子的光致发光特性,以及它如何提高发光强度,来测试Li+离子向Eu3+离子的能量转移。
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